Synthesis, structural characterization" and reactivity of a bis(phosphine)(silyl) platinum(II) complex

Wen Jin Zeng; Shi Wang; Bao Xiu Mi; Jun Feng Li; Wen Yong Lai; Yong Hua Li; Lian Hui Wang; Wei Huang

doi:10.1080/00958972.2015.1099635

Synthesis, structural characterization" and reactivity of a bis(phosphine)(silyl) platinum(II) complex

Wen Jin Zeng, Shi Wang, Bao Xiu Mi, Jun Feng Li, Wen Yong Lai, Yong Hua Li, Lian Hui Wang, Wei Huang

Nanjing University of Posts and Telecommunications

科研成果: 期刊稿件 › 文章 › 同行评审

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Treatment of 1,2-C₆H₄(SiMe₂H)(SiH₃) (1) with Pt(dcpe)(PEt₃)₂ (dcpe = Cy₂PCH₂CH₂PCy₂) in dry toluene at room temperature in the ratio of 1: 1 leads to {1,2-C₆H₄(SiMe₂)(SiH₂)}Pt^II(dcpe) (2), which can react with sterically unhindered alcohol to form a dimethoxy substituted silyl platinum(II) compound (3). There are only five examples of bis(silyl) platinum(II) complexes prepared from this silyl ligand with such structural features registered in the Cambridge Structural Database. The structures of 2 and 3 were unambiguously determined by single-crystal X-ray analysis and multinuclear NMR spectroscopic studies.

源语言	英语
页（从-至）	4203-4211
页数	9
期刊	Journal of Coordination Chemistry
卷	68
期	23
DOI	https://doi.org/10.1080/00958972.2015.1099635
出版状态	已出版 - 2 12月 2015
已对外发布	是

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title = "Synthesis, structural characterization{"} and reactivity of a bis(phosphine)(silyl) platinum(II) complex",

abstract = "Treatment of 1,2-C6H4(SiMe2H)(SiH3) (1) with Pt(dcpe)(PEt3)2 (dcpe = Cy2PCH2CH2PCy2) in dry toluene at room temperature in the ratio of 1: 1 leads to {1,2-C6H4(SiMe2)(SiH2)}PtII(dcpe) (2), which can react with sterically unhindered alcohol to form a dimethoxy substituted silyl platinum(II) compound (3). There are only five examples of bis(silyl) platinum(II) complexes prepared from this silyl ligand with such structural features registered in the Cambridge Structural Database. The structures of 2 and 3 were unambiguously determined by single-crystal X-ray analysis and multinuclear NMR spectroscopic studies.",

keywords = "Chelating, Platinum, Silyl",

author = "Zeng, {Wen Jin} and Shi Wang and Mi, {Bao Xiu} and Li, {Jun Feng} and Lai, {Wen Yong} and Li, {Yong Hua} and Wang, {Lian Hui} and Wei Huang",

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doi = "10.1080/00958972.2015.1099635",

language = "英语",

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T1 - Synthesis, structural characterization" and reactivity of a bis(phosphine)(silyl) platinum(II) complex

AU - Zeng, Wen Jin

AU - Wang, Shi

AU - Mi, Bao Xiu

AU - Li, Jun Feng

AU - Lai, Wen Yong

AU - Li, Yong Hua

AU - Wang, Lian Hui

AU - Huang, Wei

PY - 2015/12/2

Y1 - 2015/12/2

N2 - Treatment of 1,2-C6H4(SiMe2H)(SiH3) (1) with Pt(dcpe)(PEt3)2 (dcpe = Cy2PCH2CH2PCy2) in dry toluene at room temperature in the ratio of 1: 1 leads to {1,2-C6H4(SiMe2)(SiH2)}PtII(dcpe) (2), which can react with sterically unhindered alcohol to form a dimethoxy substituted silyl platinum(II) compound (3). There are only five examples of bis(silyl) platinum(II) complexes prepared from this silyl ligand with such structural features registered in the Cambridge Structural Database. The structures of 2 and 3 were unambiguously determined by single-crystal X-ray analysis and multinuclear NMR spectroscopic studies.

AB - Treatment of 1,2-C6H4(SiMe2H)(SiH3) (1) with Pt(dcpe)(PEt3)2 (dcpe = Cy2PCH2CH2PCy2) in dry toluene at room temperature in the ratio of 1: 1 leads to {1,2-C6H4(SiMe2)(SiH2)}PtII(dcpe) (2), which can react with sterically unhindered alcohol to form a dimethoxy substituted silyl platinum(II) compound (3). There are only five examples of bis(silyl) platinum(II) complexes prepared from this silyl ligand with such structural features registered in the Cambridge Structural Database. The structures of 2 and 3 were unambiguously determined by single-crystal X-ray analysis and multinuclear NMR spectroscopic studies.

KW - Chelating

KW - Platinum

KW - Silyl

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SN - 0095-8972

VL - 68

SP - 4203

EP - 4211

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 23

ER -

Synthesis, structural characterization" and reactivity of a bis(phosphine)(silyl) platinum(II) complex

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