Synthesis, structural characterization" and reactivity of a bis(phosphine)(silyl) platinum(II) complex

Wen Jin Zeng; Shi Wang; Bao Xiu Mi; Jun Feng Li; Wen Yong Lai; Yong Hua Li; Lian Hui Wang; Wei Huang

doi:10.1080/00958972.2015.1099635

Synthesis, structural characterization" and reactivity of a bis(phosphine)(silyl) platinum(II) complex

Wen Jin Zeng, Shi Wang, Bao Xiu Mi, Jun Feng Li, Wen Yong Lai, Yong Hua Li, Lian Hui Wang, Wei Huang

Nanjing University of Posts and Telecommunications

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Treatment of 1,2-C₆H₄(SiMe₂H)(SiH₃) (1) with Pt(dcpe)(PEt₃)₂ (dcpe = Cy₂PCH₂CH₂PCy₂) in dry toluene at room temperature in the ratio of 1: 1 leads to {1,2-C₆H₄(SiMe₂)(SiH₂)}Pt^II(dcpe) (2), which can react with sterically unhindered alcohol to form a dimethoxy substituted silyl platinum(II) compound (3). There are only five examples of bis(silyl) platinum(II) complexes prepared from this silyl ligand with such structural features registered in the Cambridge Structural Database. The structures of 2 and 3 were unambiguously determined by single-crystal X-ray analysis and multinuclear NMR spectroscopic studies.

Original language	English
Pages (from-to)	4203-4211
Number of pages	9
Journal	Journal of Coordination Chemistry
Volume	68
Issue number	23
DOIs	https://doi.org/10.1080/00958972.2015.1099635
State	Published - 2 Dec 2015
Externally published	Yes

Keywords

Chelating
Platinum
Silyl

Access to Document

10.1080/00958972.2015.1099635

Cite this

@article{bc3f24ebb4a24834953197b81e73c1e0,

title = "Synthesis, structural characterization{"} and reactivity of a bis(phosphine)(silyl) platinum(II) complex",

abstract = "Treatment of 1,2-C6H4(SiMe2H)(SiH3) (1) with Pt(dcpe)(PEt3)2 (dcpe = Cy2PCH2CH2PCy2) in dry toluene at room temperature in the ratio of 1: 1 leads to {1,2-C6H4(SiMe2)(SiH2)}PtII(dcpe) (2), which can react with sterically unhindered alcohol to form a dimethoxy substituted silyl platinum(II) compound (3). There are only five examples of bis(silyl) platinum(II) complexes prepared from this silyl ligand with such structural features registered in the Cambridge Structural Database. The structures of 2 and 3 were unambiguously determined by single-crystal X-ray analysis and multinuclear NMR spectroscopic studies.",

keywords = "Chelating, Platinum, Silyl",

author = "Zeng, {Wen Jin} and Shi Wang and Mi, {Bao Xiu} and Li, {Jun Feng} and Lai, {Wen Yong} and Li, {Yong Hua} and Wang, {Lian Hui} and Wei Huang",

note = "Publisher Copyright: {\textcopyright} 2015 Taylor and Francis.",

year = "2015",

month = dec,

day = "2",

doi = "10.1080/00958972.2015.1099635",

language = "英语",

volume = "68",

pages = "4203--4211",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "23",

}

TY - JOUR

T1 - Synthesis, structural characterization" and reactivity of a bis(phosphine)(silyl) platinum(II) complex

AU - Zeng, Wen Jin

AU - Wang, Shi

AU - Mi, Bao Xiu

AU - Li, Jun Feng

AU - Lai, Wen Yong

AU - Li, Yong Hua

AU - Wang, Lian Hui

AU - Huang, Wei

PY - 2015/12/2

Y1 - 2015/12/2

N2 - Treatment of 1,2-C6H4(SiMe2H)(SiH3) (1) with Pt(dcpe)(PEt3)2 (dcpe = Cy2PCH2CH2PCy2) in dry toluene at room temperature in the ratio of 1: 1 leads to {1,2-C6H4(SiMe2)(SiH2)}PtII(dcpe) (2), which can react with sterically unhindered alcohol to form a dimethoxy substituted silyl platinum(II) compound (3). There are only five examples of bis(silyl) platinum(II) complexes prepared from this silyl ligand with such structural features registered in the Cambridge Structural Database. The structures of 2 and 3 were unambiguously determined by single-crystal X-ray analysis and multinuclear NMR spectroscopic studies.

AB - Treatment of 1,2-C6H4(SiMe2H)(SiH3) (1) with Pt(dcpe)(PEt3)2 (dcpe = Cy2PCH2CH2PCy2) in dry toluene at room temperature in the ratio of 1: 1 leads to {1,2-C6H4(SiMe2)(SiH2)}PtII(dcpe) (2), which can react with sterically unhindered alcohol to form a dimethoxy substituted silyl platinum(II) compound (3). There are only five examples of bis(silyl) platinum(II) complexes prepared from this silyl ligand with such structural features registered in the Cambridge Structural Database. The structures of 2 and 3 were unambiguously determined by single-crystal X-ray analysis and multinuclear NMR spectroscopic studies.

KW - Chelating

KW - Platinum

KW - Silyl

UR - http://www.scopus.com/inward/record.url?scp=84947924746&partnerID=8YFLogxK

U2 - 10.1080/00958972.2015.1099635

DO - 10.1080/00958972.2015.1099635

M3 - 文章

AN - SCOPUS:84947924746

SN - 0095-8972

VL - 68

SP - 4203

EP - 4211

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 23

ER -

Synthesis, structural characterization" and reactivity of a bis(phosphine)(silyl) platinum(II) complex

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this