Post-Synthetic Modification of Zirconium Metal-Organic Frameworks for Adsorption and Separation of Light Hydrocarbons

Huihui He; Bingbing Guo; Yang Liu; Liangliang Zhang; Wei Huang

doi:10.1021/acs.cgd.0c00690

Post-Synthetic Modification of Zirconium Metal-Organic Frameworks for Adsorption and Separation of Light Hydrocarbons

Huihui He, Bingbing Guo, Yang Liu, Liangliang Zhang, Wei Huang

柔性电子研究院

科研成果: 期刊稿件 › 文章 › 同行评审

13 引用（Scopus）

摘要

Different functionalization of MOFs can lead to different structure-activity relationships. Flexible ligands make it easier and more diverse to assemble MOFs. The auxiliary ligand fumarate (FA) was inserted successfully into PCN-207 because of the flexibility of the primary linker and unsaturated Zr6 cluster via the post-modification method. Moreover, the successfully synthesized (4,10)-connected stable PCN-207-FA exhibited excellent thermal/chemical stability and better adsorption/separation performance of light hydrocarbons than that of PCN-207 and PCN-207-BDC, which provide guidance for inserting multiple ligands into MOFs and reveal the importance of structure-activity relationships.

源语言	英语
页（从-至）	4882-4885
页数	4
期刊	Crystal Growth and Design
卷	20
期	8
DOI	https://doi.org/10.1021/acs.cgd.0c00690
出版状态	已出版 - 5 8月 2020

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title = "Post-Synthetic Modification of Zirconium Metal-Organic Frameworks for Adsorption and Separation of Light Hydrocarbons",

abstract = "Different functionalization of MOFs can lead to different structure-activity relationships. Flexible ligands make it easier and more diverse to assemble MOFs. The auxiliary ligand fumarate (FA) was inserted successfully into PCN-207 because of the flexibility of the primary linker and unsaturated Zr6 cluster via the post-modification method. Moreover, the successfully synthesized (4,10)-connected stable PCN-207-FA exhibited excellent thermal/chemical stability and better adsorption/separation performance of light hydrocarbons than that of PCN-207 and PCN-207-BDC, which provide guidance for inserting multiple ligands into MOFs and reveal the importance of structure-activity relationships.",

author = "Huihui He and Bingbing Guo and Yang Liu and Liangliang Zhang and Wei Huang",

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doi = "10.1021/acs.cgd.0c00690",

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AU - He, Huihui

AU - Guo, Bingbing

AU - Liu, Yang

AU - Zhang, Liangliang

AU - Huang, Wei

PY - 2020/8/5

Y1 - 2020/8/5

N2 - Different functionalization of MOFs can lead to different structure-activity relationships. Flexible ligands make it easier and more diverse to assemble MOFs. The auxiliary ligand fumarate (FA) was inserted successfully into PCN-207 because of the flexibility of the primary linker and unsaturated Zr6 cluster via the post-modification method. Moreover, the successfully synthesized (4,10)-connected stable PCN-207-FA exhibited excellent thermal/chemical stability and better adsorption/separation performance of light hydrocarbons than that of PCN-207 and PCN-207-BDC, which provide guidance for inserting multiple ligands into MOFs and reveal the importance of structure-activity relationships.

AB - Different functionalization of MOFs can lead to different structure-activity relationships. Flexible ligands make it easier and more diverse to assemble MOFs. The auxiliary ligand fumarate (FA) was inserted successfully into PCN-207 because of the flexibility of the primary linker and unsaturated Zr6 cluster via the post-modification method. Moreover, the successfully synthesized (4,10)-connected stable PCN-207-FA exhibited excellent thermal/chemical stability and better adsorption/separation performance of light hydrocarbons than that of PCN-207 and PCN-207-BDC, which provide guidance for inserting multiple ligands into MOFs and reveal the importance of structure-activity relationships.

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JO - Crystal Growth and Design

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Post-Synthetic Modification of Zirconium Metal-Organic Frameworks for Adsorption and Separation of Light Hydrocarbons

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