Post-Synthetic Modification of Zirconium Metal-Organic Frameworks for Adsorption and Separation of Light Hydrocarbons

Huihui He; Bingbing Guo; Yang Liu; Liangliang Zhang; Wei Huang

doi:10.1021/acs.cgd.0c00690

Post-Synthetic Modification of Zirconium Metal-Organic Frameworks for Adsorption and Separation of Light Hydrocarbons

Huihui He, Bingbing Guo, Yang Liu, Liangliang Zhang, Wei Huang

Institute of Flexible Electronics

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Different functionalization of MOFs can lead to different structure-activity relationships. Flexible ligands make it easier and more diverse to assemble MOFs. The auxiliary ligand fumarate (FA) was inserted successfully into PCN-207 because of the flexibility of the primary linker and unsaturated Zr6 cluster via the post-modification method. Moreover, the successfully synthesized (4,10)-connected stable PCN-207-FA exhibited excellent thermal/chemical stability and better adsorption/separation performance of light hydrocarbons than that of PCN-207 and PCN-207-BDC, which provide guidance for inserting multiple ligands into MOFs and reveal the importance of structure-activity relationships.

Original language	English
Pages (from-to)	4882-4885
Number of pages	4
Journal	Crystal Growth and Design
Volume	20
Issue number	8
DOIs	https://doi.org/10.1021/acs.cgd.0c00690
State	Published - 5 Aug 2020

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title = "Post-Synthetic Modification of Zirconium Metal-Organic Frameworks for Adsorption and Separation of Light Hydrocarbons",

abstract = "Different functionalization of MOFs can lead to different structure-activity relationships. Flexible ligands make it easier and more diverse to assemble MOFs. The auxiliary ligand fumarate (FA) was inserted successfully into PCN-207 because of the flexibility of the primary linker and unsaturated Zr6 cluster via the post-modification method. Moreover, the successfully synthesized (4,10)-connected stable PCN-207-FA exhibited excellent thermal/chemical stability and better adsorption/separation performance of light hydrocarbons than that of PCN-207 and PCN-207-BDC, which provide guidance for inserting multiple ligands into MOFs and reveal the importance of structure-activity relationships.",

author = "Huihui He and Bingbing Guo and Yang Liu and Liangliang Zhang and Wei Huang",

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T1 - Post-Synthetic Modification of Zirconium Metal-Organic Frameworks for Adsorption and Separation of Light Hydrocarbons

AU - He, Huihui

AU - Guo, Bingbing

AU - Liu, Yang

AU - Zhang, Liangliang

AU - Huang, Wei

PY - 2020/8/5

Y1 - 2020/8/5

N2 - Different functionalization of MOFs can lead to different structure-activity relationships. Flexible ligands make it easier and more diverse to assemble MOFs. The auxiliary ligand fumarate (FA) was inserted successfully into PCN-207 because of the flexibility of the primary linker and unsaturated Zr6 cluster via the post-modification method. Moreover, the successfully synthesized (4,10)-connected stable PCN-207-FA exhibited excellent thermal/chemical stability and better adsorption/separation performance of light hydrocarbons than that of PCN-207 and PCN-207-BDC, which provide guidance for inserting multiple ligands into MOFs and reveal the importance of structure-activity relationships.

AB - Different functionalization of MOFs can lead to different structure-activity relationships. Flexible ligands make it easier and more diverse to assemble MOFs. The auxiliary ligand fumarate (FA) was inserted successfully into PCN-207 because of the flexibility of the primary linker and unsaturated Zr6 cluster via the post-modification method. Moreover, the successfully synthesized (4,10)-connected stable PCN-207-FA exhibited excellent thermal/chemical stability and better adsorption/separation performance of light hydrocarbons than that of PCN-207 and PCN-207-BDC, which provide guidance for inserting multiple ligands into MOFs and reveal the importance of structure-activity relationships.

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SN - 1528-7483

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JO - Crystal Growth and Design

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ER -

Post-Synthetic Modification of Zirconium Metal-Organic Frameworks for Adsorption and Separation of Light Hydrocarbons

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