Synthesis and structural studies of a rare bis(phosphine) (hydrido) (silyl) platinum(II) complex containing a Si-Si single bond

Shi Wang, Xiao Feng Yu, Nan Li, Tao Yang, Wen Yong Lai, Bao Xiu Mi, Jun Feng Li, Yong Hua Li, Lian Hui Wang, Wei Huang

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7 引用 (Scopus)

摘要

Treatment of the unsymmetric disilane (SiH3) (SiMeBut 2) (1) containing one Si-Si single bond with Pt(dcpe) (PEt3)2 (dcpe = Cy2PCH2CH2PCy2) in the ratio of 1:1 leads to a stable disilanylplatinum hydride complex {(SiH2) (SiMeBut 2)}(H)- PtII(dcpe) (2), which is one of the very few examples of bis(phosphine) (hydrido) platinum(II) complexes bearing silyl ligands with Si-Si single bonds structurally characterized by single crystal X-ray analysis and multinuclear NMR spectroscopic studies.

源语言英语
页(从-至)113-116
页数4
期刊Journal of Organometallic Chemistry
776
DOI
出版状态已出版 - 15 1月 2015
已对外发布

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