Synthesis and structural studies of a rare bis(phosphine) (hydrido) (silyl) platinum(II) complex containing a Si-Si single bond

Shi Wang; Xiao Feng Yu; Nan Li; Tao Yang; Wen Yong Lai; Bao Xiu Mi; Jun Feng Li; Yong Hua Li; Lian Hui Wang; Wei Huang

doi:10.1016/j.jorganchem.2014.11.003

Synthesis and structural studies of a rare bis(phosphine) (hydrido) (silyl) platinum(II) complex containing a Si-Si single bond

Shi Wang, Xiao Feng Yu, Nan Li, Tao Yang, Wen Yong Lai, Bao Xiu Mi, Jun Feng Li, Yong Hua Li, Lian Hui Wang, Wei Huang

Research output: Contribution to journal › Short survey › peer-review

7 Scopus citations

Abstract

Treatment of the unsymmetric disilane (SiH₃) (SiMeBu^t ₂) (1) containing one Si-Si single bond with Pt(dcpe) (PEt₃)₂ (dcpe = Cy₂PCH₂CH₂PCy₂) in the ratio of 1:1 leads to a stable disilanylplatinum hydride complex {(SiH₂) (SiMeBu^t ₂)}(H)- Pt^II(dcpe) (2), which is one of the very few examples of bis(phosphine) (hydrido) platinum(II) complexes bearing silyl ligands with Si-Si single bonds structurally characterized by single crystal X-ray analysis and multinuclear NMR spectroscopic studies.

Original language	English
Pages (from-to)	113-116
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	776
DOIs	https://doi.org/10.1016/j.jorganchem.2014.11.003
State	Published - 15 Jan 2015
Externally published	Yes

Keywords

Hydrido
Multinuclear NMR
Platinum
Unsymmetric disilane

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10.1016/j.jorganchem.2014.11.003

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title = "Synthesis and structural studies of a rare bis(phosphine) (hydrido) (silyl) platinum(II) complex containing a Si-Si single bond",

abstract = "Treatment of the unsymmetric disilane (SiH3) (SiMeBut 2) (1) containing one Si-Si single bond with Pt(dcpe) (PEt3)2 (dcpe = Cy2PCH2CH2PCy2) in the ratio of 1:1 leads to a stable disilanylplatinum hydride complex {(SiH2) (SiMeBut 2)}(H)- PtII(dcpe) (2), which is one of the very few examples of bis(phosphine) (hydrido) platinum(II) complexes bearing silyl ligands with Si-Si single bonds structurally characterized by single crystal X-ray analysis and multinuclear NMR spectroscopic studies.",

keywords = "Hydrido, Multinuclear NMR, Platinum, Unsymmetric disilane",

author = "Shi Wang and Yu, {Xiao Feng} and Nan Li and Tao Yang and Lai, {Wen Yong} and Mi, {Bao Xiu} and Li, {Jun Feng} and Li, {Yong Hua} and Wang, {Lian Hui} and Wei Huang",

year = "2015",

month = jan,

day = "15",

doi = "10.1016/j.jorganchem.2014.11.003",

language = "英语",

volume = "776",

pages = "113--116",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Synthesis and structural studies of a rare bis(phosphine) (hydrido) (silyl) platinum(II) complex containing a Si-Si single bond

AU - Wang, Shi

AU - Yu, Xiao Feng

AU - Li, Nan

AU - Yang, Tao

AU - Lai, Wen Yong

AU - Mi, Bao Xiu

AU - Li, Jun Feng

AU - Li, Yong Hua

AU - Wang, Lian Hui

AU - Huang, Wei

PY - 2015/1/15

Y1 - 2015/1/15

N2 - Treatment of the unsymmetric disilane (SiH3) (SiMeBut 2) (1) containing one Si-Si single bond with Pt(dcpe) (PEt3)2 (dcpe = Cy2PCH2CH2PCy2) in the ratio of 1:1 leads to a stable disilanylplatinum hydride complex {(SiH2) (SiMeBut 2)}(H)- PtII(dcpe) (2), which is one of the very few examples of bis(phosphine) (hydrido) platinum(II) complexes bearing silyl ligands with Si-Si single bonds structurally characterized by single crystal X-ray analysis and multinuclear NMR spectroscopic studies.

AB - Treatment of the unsymmetric disilane (SiH3) (SiMeBut 2) (1) containing one Si-Si single bond with Pt(dcpe) (PEt3)2 (dcpe = Cy2PCH2CH2PCy2) in the ratio of 1:1 leads to a stable disilanylplatinum hydride complex {(SiH2) (SiMeBut 2)}(H)- PtII(dcpe) (2), which is one of the very few examples of bis(phosphine) (hydrido) platinum(II) complexes bearing silyl ligands with Si-Si single bonds structurally characterized by single crystal X-ray analysis and multinuclear NMR spectroscopic studies.

KW - Hydrido

KW - Multinuclear NMR

KW - Platinum

KW - Unsymmetric disilane

UR - http://www.scopus.com/inward/record.url?scp=84949133684&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2014.11.003

DO - 10.1016/j.jorganchem.2014.11.003

M3 - 短篇评述

AN - SCOPUS:84949133684

SN - 0022-328X

VL - 776

SP - 113

EP - 116

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Synthesis and structural studies of a rare bis(phosphine) (hydrido) (silyl) platinum(II) complex containing a Si-Si single bond

Abstract

Keywords

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