(enH2)4.5[In(AsVS4) 3][As2III(μ-S2)S3]Cl and (enH2)MnAsIIIAsVS6: Two thioarsenates(iii, v) with mixed-valent optical properties

Ke Zhao Du, Mei Ling Feng, Xing Hui Qi, Zu Ju Ma, Long Hua Li, Jian Rong Li, Cheng Feng Du, Guo Dong Zou, Xiao Ying Huang

科研成果: 期刊稿件文章同行评审

17 引用 (Scopus)

摘要

Two mixed-valent thioarsenates, namely (enH2) 4.5[In(AsVS4)3][As2 III(μ-S2)S3]Cl (1) and (enH 2)MnAsIIIAsVS6 (2) (en = ethylenediamine), have been solvothermally synthesized and characterized. Thermal stability, magnetic and mixed-valent optical properties, as well as theoretical band structures and DOSs, of 1 and 2 have also been studied.

源语言英语
页(从-至)2733-2736
页数4
期刊Dalton Transactions
43
7
DOI
出版状态已出版 - 21 2月 2014
已对外发布

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