(enH2)4.5[In(AsVS4) 3][As2III(μ-S2)S3]Cl and (enH2)MnAsIIIAsVS6: Two thioarsenates(iii, v) with mixed-valent optical properties

Ke Zhao Du; Mei Ling Feng; Xing Hui Qi; Zu Ju Ma; Long Hua Li; Jian Rong Li; Cheng Feng Du; Guo Dong Zou; Xiao Ying Huang

doi:10.1039/c3dt53048e

(enH₂)_4.5[In(As^VS₄) ₃][As₂^III(μ-S₂)S₃]Cl and (enH₂)MnAs^IIIAs^VS₆: Two thioarsenates(iii, v) with mixed-valent optical properties

Ke Zhao Du, Mei Ling Feng, Xing Hui Qi, Zu Ju Ma, Long Hua Li, Jian Rong Li, Cheng Feng Du, Guo Dong Zou, Xiao Ying Huang

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Two mixed-valent thioarsenates, namely (enH₂) _4.5[In(As^VS₄)₃][As₂ ^III(μ-S₂)S₃]Cl (1) and (enH ₂)MnAs^IIIAs^VS₆ (2) (en = ethylenediamine), have been solvothermally synthesized and characterized. Thermal stability, magnetic and mixed-valent optical properties, as well as theoretical band structures and DOSs, of 1 and 2 have also been studied.

Original language	English
Pages (from-to)	2733-2736
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	7
DOIs	https://doi.org/10.1039/c3dt53048e
State	Published - 21 Feb 2014
Externally published	Yes

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title = "(enH2)4.5[In(AsVS4) 3][As2III(μ-S2)S3]Cl and (enH2)MnAsIIIAsVS6: Two thioarsenates(iii, v) with mixed-valent optical properties",

abstract = "Two mixed-valent thioarsenates, namely (enH2) 4.5[In(AsVS4)3][As2 III(μ-S2)S3]Cl (1) and (enH 2)MnAsIIIAsVS6 (2) (en = ethylenediamine), have been solvothermally synthesized and characterized. Thermal stability, magnetic and mixed-valent optical properties, as well as theoretical band structures and DOSs, of 1 and 2 have also been studied.",

author = "Du, {Ke Zhao} and Feng, {Mei Ling} and Qi, {Xing Hui} and Ma, {Zu Ju} and Li, {Long Hua} and Li, {Jian Rong} and Du, {Cheng Feng} and Zou, {Guo Dong} and Huang, {Xiao Ying}",

year = "2014",

month = feb,

day = "21",

doi = "10.1039/c3dt53048e",

language = "英语",

volume = "43",

pages = "2733--2736",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "7",

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TY - JOUR

T1 - (enH2)4.5[In(AsVS4) 3][As2III(μ-S2)S3]Cl and (enH2)MnAsIIIAsVS6

T2 - Two thioarsenates(iii, v) with mixed-valent optical properties

AU - Du, Ke Zhao

AU - Feng, Mei Ling

AU - Qi, Xing Hui

AU - Ma, Zu Ju

AU - Li, Long Hua

AU - Li, Jian Rong

AU - Du, Cheng Feng

AU - Zou, Guo Dong

AU - Huang, Xiao Ying

PY - 2014/2/21

Y1 - 2014/2/21

N2 - Two mixed-valent thioarsenates, namely (enH2) 4.5[In(AsVS4)3][As2 III(μ-S2)S3]Cl (1) and (enH 2)MnAsIIIAsVS6 (2) (en = ethylenediamine), have been solvothermally synthesized and characterized. Thermal stability, magnetic and mixed-valent optical properties, as well as theoretical band structures and DOSs, of 1 and 2 have also been studied.

AB - Two mixed-valent thioarsenates, namely (enH2) 4.5[In(AsVS4)3][As2 III(μ-S2)S3]Cl (1) and (enH 2)MnAsIIIAsVS6 (2) (en = ethylenediamine), have been solvothermally synthesized and characterized. Thermal stability, magnetic and mixed-valent optical properties, as well as theoretical band structures and DOSs, of 1 and 2 have also been studied.

UR - http://www.scopus.com/inward/record.url?scp=84892921268&partnerID=8YFLogxK

U2 - 10.1039/c3dt53048e

DO - 10.1039/c3dt53048e

M3 - 文章

AN - SCOPUS:84892921268

SN - 1477-9226

VL - 43

SP - 2733

EP - 2736

JO - Dalton Transactions

JF - Dalton Transactions

IS - 7

ER -

(enH₂)_4.5[In(As^VS₄) ₃][As₂^III(μ-S₂)S₃]Cl and (enH₂)MnAs^IIIAs^VS₆: Two thioarsenates(iii, v) with mixed-valent optical properties

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