(enH2)4.5[In(AsVS4) 3][As2III(μ-S2)S3]Cl and (enH2)MnAsIIIAsVS6: Two thioarsenates(iii, v) with mixed-valent optical properties

Ke Zhao Du, Mei Ling Feng, Xing Hui Qi, Zu Ju Ma, Long Hua Li, Jian Rong Li, Cheng Feng Du, Guo Dong Zou, Xiao Ying Huang

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

Two mixed-valent thioarsenates, namely (enH2) 4.5[In(AsVS4)3][As2 III(μ-S2)S3]Cl (1) and (enH 2)MnAsIIIAsVS6 (2) (en = ethylenediamine), have been solvothermally synthesized and characterized. Thermal stability, magnetic and mixed-valent optical properties, as well as theoretical band structures and DOSs, of 1 and 2 have also been studied.

Original languageEnglish
Pages (from-to)2733-2736
Number of pages4
JournalDalton Transactions
Volume43
Issue number7
DOIs
StatePublished - 21 Feb 2014
Externally publishedYes

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