Chiral assembly of dodecahedral cavities into porous metal–organic frameworks

Hui Yang; Fei Wang; Yao Kang; Tie Hu Li; Jian Zhang

doi:10.1039/c2cc35024f

Chiral assembly of dodecahedral cavities into porous metal–organic frameworks

Hui Yang, Fei Wang, Yao Kang, Tie Hu Li, Jian Zhang

材料学院

科研成果: 期刊稿件 › 文章 › 同行评审

45 引用（Scopus）

摘要

Corner-sharing assembly of dodecahedral cavities with both paddle-wheel [M₂(CO₂)₄] units and trimeric [M₃(μ₃-OH)(CO₂)₆] units leads to two isomorphous chiral microporous metal–organic frameworks, where the heterometallic framework has high surface area and excellent CO₂/N₂ adsorption selectivity.

源语言	英语
页（从-至）	9424-9426
页数	3
期刊	Chemical Communications
卷	48
期	75
DOI	https://doi.org/10.1039/c2cc35024f
出版状态	已出版 - 22 8月 2012

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10.1039/c2cc35024f

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abstract = "Corner-sharing assembly of dodecahedral cavities with both paddle-wheel [M2(CO2)4] units and trimeric [M3(μ3-OH)(CO2)6] units leads to two isomorphous chiral microporous metal–organic frameworks, where the heterometallic framework has high surface area and excellent CO2/N2 adsorption selectivity.",

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AU - Yang, Hui

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AU - Kang, Yao

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N2 - Corner-sharing assembly of dodecahedral cavities with both paddle-wheel [M2(CO2)4] units and trimeric [M3(μ3-OH)(CO2)6] units leads to two isomorphous chiral microporous metal–organic frameworks, where the heterometallic framework has high surface area and excellent CO2/N2 adsorption selectivity.

AB - Corner-sharing assembly of dodecahedral cavities with both paddle-wheel [M2(CO2)4] units and trimeric [M3(μ3-OH)(CO2)6] units leads to two isomorphous chiral microporous metal–organic frameworks, where the heterometallic framework has high surface area and excellent CO2/N2 adsorption selectivity.

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Chiral assembly of dodecahedral cavities into porous metal–organic frameworks

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