Abstract
Corner-sharing assembly of dodecahedral cavities with both paddle-wheel [M2(CO2)4] units and trimeric [M3(μ3-OH)(CO2)6] units leads to two isomorphous chiral microporous metal–organic frameworks, where the heterometallic framework has high surface area and excellent CO2/N2 adsorption selectivity.
Original language | English |
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Pages (from-to) | 9424-9426 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 48 |
Issue number | 75 |
DOIs | |
State | Published - 22 Aug 2012 |