Access to Enantioenriched Organosilanes from Enals and β-Silyl Enones: Carbene Organocatalysis

Yuxia Zhang, Jie Huang, Yingying Guo, Lin Li, Zhenqian Fu, Wei Huang

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54 引用 (Scopus)

摘要

Herein, an efficient route to enantioenriched organosilanes, containing two consecutive stereogenic centers, from enals and β-silyl enones under carbene organocatalysis is described. Under mild reaction conditions, this transition-metal-free strategy exhibits a broad substrate scope, and excellent diastereo- and enantioselectivity.

源语言英语
页(从-至)4594-4598
页数5
期刊Angewandte Chemie - International Edition
57
17
DOI
出版状态已出版 - 16 4月 2018

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