Viscoelastic behavior of poly(methyl methacrylate-co-methyl acrylate) random copolymer studied by dynamic mechanical analysis and nanoindentation

Keran Li, Bijin Xiong, Jichao Qiao, Ya Cao

科研成果: 期刊稿件文章同行评审

1 引用 (Scopus)

摘要

The viscoelastic behavior of poly(methyl methacrylate) (PMMA) homopolymer and poly(methyl methacrylate-co-methyl acrylate) random copolymers was characterized by dynamic mechanical analysis and nanoindentation. Differential scanning calorimetric results showed only one glass transition, indicating the random distribution of comonomers in the copolymers. The a relaxation temperature (Tα) and activation energy (Hα) decreased with increasing content of methyl acrylate monomers (CMA%). The β relaxation temperature (Tβ) also decreased whereas the activation energy (Hβ) showed only small variations compared with Hα. Moreover, the indention displacement and creep compliance strongly depended on CMA%. Two creep stages were found in the creep compliance curves.

源语言英语
页(从-至)1297-1308
页数12
期刊Journal of Macromolecular Science, Part B: Physics
54
11
DOI
出版状态已出版 - 2015
已对外发布

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