TY - JOUR
T1 - Three alkaline earth metal-organic frameworks based on fluorene-containing carboxylates
T2 - syntheses, structures and properties
AU - Zhou, Xinhui
AU - Chen, Qiang
AU - Li, Liang
AU - Yang, Tao
AU - Wang, Jin
AU - Huang, Wei
N1 - Publisher Copyright:
© 2016, Science China Press and Springer-Verlag Berlin Heidelberg.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - Three metal-organic frameworks, {[Mg2(MFDA)2(DMF)3]·0.5H2O}n (1), {[Ca(MFDA)(DMF)(H2O)]·0.5DMF}n (2) and [Ca(MFDA)(DMF)2]n (3) (DMF=N,N-dimethylformamide) have been synthesized by the solvothermal reactions between the ligand 9,9-dimethylfluorene-2,7-dicarboxylic acid (H2MFDA) and the corresponding metal salts, respectively. The single crystal X-ray structural analyses reveal that compounds 1–3 display three-dimensional structures based on the M(II)–O–C chains. It is interesting that the MFDA ligands in 1–3 have different dihedral angles between the two carboxylate groups ranging from 9.9(1)° to 41.8(2)°. All of compounds exhibit strong ligand-centered blue emissions under UV lights. Their thermal properties have also been studied.
AB - Three metal-organic frameworks, {[Mg2(MFDA)2(DMF)3]·0.5H2O}n (1), {[Ca(MFDA)(DMF)(H2O)]·0.5DMF}n (2) and [Ca(MFDA)(DMF)2]n (3) (DMF=N,N-dimethylformamide) have been synthesized by the solvothermal reactions between the ligand 9,9-dimethylfluorene-2,7-dicarboxylic acid (H2MFDA) and the corresponding metal salts, respectively. The single crystal X-ray structural analyses reveal that compounds 1–3 display three-dimensional structures based on the M(II)–O–C chains. It is interesting that the MFDA ligands in 1–3 have different dihedral angles between the two carboxylate groups ranging from 9.9(1)° to 41.8(2)°. All of compounds exhibit strong ligand-centered blue emissions under UV lights. Their thermal properties have also been studied.
KW - alkaline earth
KW - coordination polymers
KW - fluorene
KW - metal-organic frameworks (MOFs)
UR - http://www.scopus.com/inward/record.url?scp=84994309557&partnerID=8YFLogxK
U2 - 10.1007/s11426-016-0291-3
DO - 10.1007/s11426-016-0291-3
M3 - 文章
AN - SCOPUS:84994309557
SN - 1674-7291
VL - 60
SP - 115
EP - 121
JO - Science China Chemistry
JF - Science China Chemistry
IS - 1
ER -