The mechanism of PEO process on Al-Si alloys in zirconate solution

Wang Ping, Dao Xin Liu, Jian Ping Li, Yong Chun Guo, Yang Zhong

科研成果: 书/报告/会议事项章节会议稿件同行评审

1 引用 (Scopus)

摘要

Zirconia coating was produced on Al-Si alloys by plasma electrolytic oxidation (PEO). The alkaline electrolyte containing Zr(OH) 4 powders was used. The composition and structure of the coating were investigated by SEM and XRD. The results show that in the initial stages of oxidation the growth of coating belongs to the stage of anodic oxidation controlled by electrochemical polarization. The growth of coating is mainly outward growth and the growth rate is faster. With elongated treated time and increased thickness of the coating, the growth of coating is mainly ingrowth. In contrast with the stage of anodization, the growth rate of plasma electrolytic oxidation is slower than anodization. The coating consists of t-ZrO 2, m-ZrO 2, α-Al 2O 3 and α-Al 2O 3.T-ZrO 2 is the main phase and distributes in outer layer of the coating, however, α-Al 2O 3 appears in inner layer of the coating. Many micro-particles appear on the coating surface with dimension of 1-2μm. In the process of plasma electrolytic oxidation, Zr(OH) 4 powders move and deposit on the mouth of plasma discharge channel under the effect of electric field force, then it is transformed to ZrO 2 by the high temperature of plasma discharge.

源语言英语
主期刊名Advanced Mechanical Design
178-181
页数4
DOI
出版状态已出版 - 2012
活动3rd international Conference on Manufacturing Science and Engineering, ICMSE 2012 - Xiamen, 中国
期限: 27 3月 201229 3月 2012

出版系列

姓名Advanced Materials Research
479-481
ISSN(印刷版)1022-6680

会议

会议3rd international Conference on Manufacturing Science and Engineering, ICMSE 2012
国家/地区中国
Xiamen
时期27/03/1229/03/12

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