The evolution of microstructure and electrical performance in doped Mn-Co and Cu-Mn oxide layers with the extended oxidation time

P. Y. Guo, H. Sun, Y. Shao, J. T. Ding, J. C. Li, M. R. Huang, S. Y. Mao, Y. X. Wang, J. F. Zhang, R. C. Long, X. H. Hou

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32 引用 (Scopus)

摘要

Mn-Co and Cu-Mn based alloy coatings are deposited on 430 SS by high energy micro-arc alloying process, and then alloy coatings are oxidized at 750 °C in air to form the spinel oxides. Some composite oxides, such as Co3O4, Mn2O3 and (Mn,Co)3O4, are formed at the initial stage of oxidation. The single-phase spinel (pure MnCo2O4) without impurity phases is only found on the surface of Co-33Mn-17Cu oxide layer with the extended oxidation time, its area-specific resistance values at 500 °C to 800 °C are low and close to that of Mn-35Cu oxide layer which mainly composed of Cu1.2Mn1.8O4 spinel.

源语言英语
文章编号108738
期刊Corrosion Science
172
DOI
出版状态已出版 - 1 8月 2020
已对外发布

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