Synthesis of HMX via Nitrolysis of DPT Catalyzed by acidic ionic liquids

Zhiyong He; Jun Luo; Chunxu Lü; Rong Xu; Jinshan Li

Synthesis of HMX via Nitrolysis of DPT Catalyzed by acidic ionic liquids

Zhiyong He, Jun Luo, Chunxu Lü, Rong Xu, Jinshan Li

科研成果: 期刊稿件 › 文章 › 同行评审

13 引用（Scopus）

摘要

The direct nitrolysis of DPT to synthesize HMX with ionic liquids (ILs) as catalysts was investigated. The results showed that [Et ₃NH] HSO ₄ was the best catalyst among 18 ILs used and the yield of HMX was up to 61% against 45% without IL. The ILs could be efficiently recovered by simple distillation and extraction after reaction without any apparent loss of catalytic activity even after 10 times recycling.

源语言	英语
页（从-至）	83-92
页数	10
期刊	Central European Journal of Energetic Materials
卷	8
期	2
出版状态	已出版 - 2011
已对外发布	是

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title = "Synthesis of HMX via Nitrolysis of DPT Catalyzed by acidic ionic liquids",

abstract = "The direct nitrolysis of DPT to synthesize HMX with ionic liquids (ILs) as catalysts was investigated. The results showed that [Et 3NH] HSO 4 was the best catalyst among 18 ILs used and the yield of HMX was up to 61% against 45% without IL. The ILs could be efficiently recovered by simple distillation and extraction after reaction without any apparent loss of catalytic activity even after 10 times recycling.",

keywords = "DPT, HMX, Ionic liquid, Nitrolysis",

author = "Zhiyong He and Jun Luo and Chunxu L{\"u} and Rong Xu and Jinshan Li",

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T1 - Synthesis of HMX via Nitrolysis of DPT Catalyzed by acidic ionic liquids

AU - He, Zhiyong

AU - Luo, Jun

AU - Lü, Chunxu

AU - Xu, Rong

AU - Li, Jinshan

PY - 2011

Y1 - 2011

N2 - The direct nitrolysis of DPT to synthesize HMX with ionic liquids (ILs) as catalysts was investigated. The results showed that [Et 3NH] HSO 4 was the best catalyst among 18 ILs used and the yield of HMX was up to 61% against 45% without IL. The ILs could be efficiently recovered by simple distillation and extraction after reaction without any apparent loss of catalytic activity even after 10 times recycling.

AB - The direct nitrolysis of DPT to synthesize HMX with ionic liquids (ILs) as catalysts was investigated. The results showed that [Et 3NH] HSO 4 was the best catalyst among 18 ILs used and the yield of HMX was up to 61% against 45% without IL. The ILs could be efficiently recovered by simple distillation and extraction after reaction without any apparent loss of catalytic activity even after 10 times recycling.

KW - DPT

KW - HMX

KW - Ionic liquid

KW - Nitrolysis

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M3 - 文章

AN - SCOPUS:83055193335

SN - 1733-7178

VL - 8

SP - 83

EP - 92

JO - Central European Journal of Energetic Materials

JF - Central European Journal of Energetic Materials

IS - 2

ER -

Synthesis of HMX via Nitrolysis of DPT Catalyzed by acidic ionic liquids

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