Synthesis and optical properties of ethynylene-linked starburst oligofluorene based on hexahexyltruxene

Qing Quan Chen, Feng Liu, Zhun Ma, Bo Peng, Wei Wei, Wei Huang

科研成果: 期刊稿件文章同行评审

8 引用 (Scopus)

摘要

New monodisperse starburst oligofluorene derivatives, which contain 5,5′,10,10′,15,15′-hexahexyltruxene as the central core linked with oligo(9,9′-dihexylfluorene) as the arms through ethynylene bridge are presented. All these compounds were prepared via Sonogashira reaction. Their molecular structures were confirmed by NMR, MALDI-TOF MS spectrometry and elementary analysis. The fluorescence spectra showed that introduction of ethynylene linker showed that the optical properties of the starburst oligofluorenes were modified. Both the absorption and the fluorescence peaks were found to be red-shifted.

源语言英语
页(从-至)3145-3148
页数4
期刊Synlett
20
DOI
出版状态已出版 - 17 12月 2007
已对外发布

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