Study on extended chain crystals of polyethylene via modulated differential scanning calorimeter

Jie Kong, Xiao Dong Fan, Yun Chuan Xie, Wen Qiang Qiao

科研成果: 期刊稿件文章同行评审

3 引用 (Scopus)

摘要

The DSC and MDSC data show that polyethylene crystallized under high pressure of 640 MPa has the crystallinity of 89.11% with melting point of 143.4°C. The POM and SEM photographs further indicate that the thickness of ECC is 200 - 280 nm. Compared to FCC, there is no recrystallization exothermic peak in the nonreversing thermograph of ECC, which suggests that there exist the perfect crystals of ECC crystallized out from the hexagonal region. The value of nonreversing endothermic enthalpy of ECC is lager than that of FCC. This clearly indicates that the melting of perfect crystals of ECC is nonreversible under ambient conditions.

源语言英语
页(从-至)178-181
页数4
期刊Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering
20
5
出版状态已出版 - 9月 2004

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