TY - JOUR
T1 - Spirocyclic aromatic hydrocarbons (SAHs) and their synthetic methodologies
AU - Xie, Ling Hai
AU - Liang, Jing
AU - Song, Juan
AU - Yin, Cheng Rong
AU - Huang, Wei
PY - 2010
Y1 - 2010
N2 - Spirocyclic aromatic hydrocarbons (SAHs) or spirocyclic arenes are functional building blocks in constructing amorphous organic/ polymeric semiconductors with high glass transition temperatures for organic electronic devices. In this review, SAHs were categorized into three classes - mono-spirocyclic aromatic hydrocarbons (MSAHs), heteroatom-containing spirocyclic aromatic hydrocarbons (HSAHs), and polyspirocyclic aromatic hydrocarbons (PSAHs) based on MSAHs and HSAHs. Various synthetic strategies of SAHs, viz., o-halobiaryl method, diarylfluorene method, dibiarylketone method, one-pot domino synthesis, tandem dilithiation method, alkyne-fused aromatization, allene method, and other related routes were summarized.
AB - Spirocyclic aromatic hydrocarbons (SAHs) or spirocyclic arenes are functional building blocks in constructing amorphous organic/ polymeric semiconductors with high glass transition temperatures for organic electronic devices. In this review, SAHs were categorized into three classes - mono-spirocyclic aromatic hydrocarbons (MSAHs), heteroatom-containing spirocyclic aromatic hydrocarbons (HSAHs), and polyspirocyclic aromatic hydrocarbons (PSAHs) based on MSAHs and HSAHs. Various synthetic strategies of SAHs, viz., o-halobiaryl method, diarylfluorene method, dibiarylketone method, one-pot domino synthesis, tandem dilithiation method, alkyne-fused aromatization, allene method, and other related routes were summarized.
KW - Cruciform π-system
KW - Light-emitting materials
KW - O-halobiaryls
KW - Organic semiconductors
KW - Spiro-compounds
KW - Spirobifluorene
UR - http://www.scopus.com/inward/record.url?scp=78649978072&partnerID=8YFLogxK
U2 - 10.2174/138527210793351599
DO - 10.2174/138527210793351599
M3 - 文章
AN - SCOPUS:78649978072
SN - 1385-2728
VL - 14
SP - 2169
EP - 2195
JO - Current Organic Chemistry
JF - Current Organic Chemistry
IS - 18
ER -