Solute redistribution during phase separation of ternary Fe–Cu–Si alloy

Ternary Fe₄₈Cu₄₈Si₄ immiscible alloy was rapidly solidified under the containerless microgravity condition inside a drop tube. Liquid phase separation took place in the alloy melt and led to the formation of various segregated structures. The core–shell structure consisting of Fe-rich and Cu-rich zones and the homogenously dispersed structure were the major structural morphologies. Phase field simulation results revealed that the two-layer core–shell was the final structure of liquid phase separation. The solute redistribution of liquid Fe₄₈Cu₄₈Si₄ alloy experienced the macroscopic solute distribution induced by liquid phase separation, the secondary phase separation within the separated liquid phases and the solute trapping during rapid solidification. Energy dispersive spectroscopy analysis showed that the solute Si was enriched in the Fe-rich zone whereas depleted in the Cu-rich zone. In addition, both αFe and (Cu) phases in the Fe-rich zone exhibited a conspicuous solute trapping effect. As compared with (Cu) phase, αFe phase had a stronger affinity with solute Si.