Recent advances in thermal analysis and stability evaluation of insensitive plastic bonded explosives (PBXs)

Qi Long Yan, Svatopluk Zeman, Ahmed Elbeih

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167 引用 (Scopus)

摘要

In this paper, several fundamental investigations published over the past decades with regard to the thermal analysis of polymer-based explosives (PBXs) have been briefly reviewed. A number of explosive fillers and polymer bases that were used as their main ingredients of PBXs are summarized herein. In addition, the calculation methods for their decomposition kinetics and thermal stability parameters are also introduced in detail. It was concluded that only PBXs based on HMX, RDX and TATB have been widely investigated, and that some other PBXs containing innovative fillers, such as CL-20, TNAZ, NTO and BCHMX are at the design stage. The isoconversional methods and model fitting procedures are usually used to analyze the discrete thermolysis processes of PBXs. In addition, their thermal stability parameters such as shelf life, explosion delay, critical temperature, thermostability threshold, 500-day cookoff temperature and approximate time to explosion could be calculated easily from the kinetic data.

源语言英语
页(从-至)1-12
页数12
期刊Thermochimica Acta
537
DOI
出版状态已出版 - 10 6月 2012
已对外发布

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