Re-Examination of the Microstructural Evolution in Undercooled Co-18.5at.%B Eutectic Alloy

The undercooling (∆T) dependencies of the solidification pathways, microstructural evo-lution, and recalescence behaviors of undercooled Co-18.5at.%B eutectic alloys were systematically explored. Up to four possible solidification pathways were identified: (1) A lamellar eutectic structure consisting of the FCC–Co and Co₃B phase forms, with extremely low ∆T; (2) The FCC–Co phase primarily forms, followed by the eutectic growth of the FCC–Co and Co₂B phases when ∆T < 100 K; (3) As the ∆T increases further, the FCC–Co phase primarily forms, followed by the metastable Co₂₃B₆ phase with the trace of an FCC–Co and Co₂₃B₆ eutectic; (4) When the ∆T increases to 277 K, the FCC–Co phase primarily forms, followed by an FCC–Co and Co₃B eutectic, which is similar in composition to the microstructure formed with low ∆T. The mechanisms of the microstructural evolution and the phase selection are interpreted on the basis of the composition segregation, the skewed coupled zone, the strain-induced transformation, and the solute trapping. Moreover, the prenucleation of the primary FCC–Co phase was also detected from an analysis of the different recalescence behaviors. The present work not only enriches our knowledge about the phase selection behavior in the undercooled Co–B system, but also provides us with guidance for controlling the microstructures and properties practically.