Poly[(μ 2-quinoline-3-carboxylato-κ 2 N:O)(μ 2-quinoline-3-carboxylato-κ 3N:O,O′) cadmium]

Xing Wang, Yong Sheng Yan, He Yi Sun, Shen Tang Wang, Chun Bo Liu

科研成果: 期刊稿件文章同行评审

摘要

In the title compound, [Cd(C 10H 6NO 2) 2] n , the Cd II atom is coordinated by three O atoms and two N atoms from four quinoline-3-carboxyl-ate (L -) ligands, leading to a distorted trigonal-bipyramidal geometry. The L - ligands link the Cd II atoms into a plane parallel to (100), with one ligand being tridentate, coordinating via the N atom and chelating a second Cd atom, and the other being bidentate, bridging two Cd atoms via the N and one O atom.. This two-dimensional network extends into a double-layer network by π-π inter-actions, with centroid-centroid distances of 3.680 (2) and 3.752 (2) Å. Another type of π-π inter-action between pyridine rings [centroid-centroid distance = 3.527 (2) Å] leads to a three-dimensional supra-molecular architecture.

源语言英语
页(从-至)m163
期刊Acta Crystallographica Section E: Structure Reports Online
68
2
DOI
出版状态已出版 - 2月 2012
已对外发布

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