摘要
In the title compound, [Cd(C 10H 6NO 2) 2] n , the Cd II atom is coordinated by three O atoms and two N atoms from four quinoline-3-carboxyl-ate (L -) ligands, leading to a distorted trigonal-bipyramidal geometry. The L - ligands link the Cd II atoms into a plane parallel to (100), with one ligand being tridentate, coordinating via the N atom and chelating a second Cd atom, and the other being bidentate, bridging two Cd atoms via the N and one O atom.. This two-dimensional network extends into a double-layer network by π-π inter-actions, with centroid-centroid distances of 3.680 (2) and 3.752 (2) Å. Another type of π-π inter-action between pyridine rings [centroid-centroid distance = 3.527 (2) Å] leads to a three-dimensional supra-molecular architecture.
源语言 | 英语 |
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页(从-至) | m163 |
期刊 | Acta Crystallographica Section E: Structure Reports Online |
卷 | 68 |
期 | 2 |
DOI | |
出版状态 | 已出版 - 2月 2012 |
已对外发布 | 是 |