TY - JOUR
T1 - Improving through-plane thermal conductivity of PDMS-based composites using highly oriented carbon fibers bridged by Al2O3 particles
AU - Huang, Ruoyu
AU - Ding, Dongliang
AU - Guo, Xiaoxiao
AU - Liu, Changjiang
AU - Li, Xinhua
AU - Jiang, Gaoxiao
AU - Zhang, Yufeng
AU - Chen, Yanhui
AU - Cai, Weiwei
AU - Zhang, Xue ao
N1 - Publisher Copyright:
© 2022 Elsevier Ltd
PY - 2022/11/10
Y1 - 2022/11/10
N2 - Efficient thermal interface materials (TIMs) are urgently needed for heat dissipation of high-power density electronics. In this study, vinyl polydimethylsiloxane (PDMS) composites with the spatial alignment of carbon fibers (CFs) bridged by Al2O3 particles were fabricated by the flow field. The through-plane thermal conductivity (TPTC) of the composites with 24 vol% CFs and 47 vol% Al2O3 loading reached 38.0 W m−1 K−1. The oriented CFs bridged by Al2O3 acted as the efficient through-plane thermal conductive network. Furthermore, the effects of shape factor (b/a), spatial angle (γ) of CFs, and CF loading (Vf) on the TPTC were quantitatively discussed by steady-state finite element simulation combined with micro-computed tomography and machine learning. The positive contribution of the increased Vf to TPTC was in competition with the negative contribution of b/a and γ, both of which increased with the increase of Vf. Moreover, b/a exerted more negative effects than γ. The PDMS composites demonstrated excellent thermal stability (Td = 407.5 °C, CTE = −55.3 × 10−6 K−1), low compress modulus (1.71 MPa), and hardness (47 (Shore C)), which made them potential candidates for TIMs. This work offers a feasible method to prepare TIMs on large scale and refreshes the thermal conduction mechanism of TIMs by introducing the influencing factors (b/a and γ).
AB - Efficient thermal interface materials (TIMs) are urgently needed for heat dissipation of high-power density electronics. In this study, vinyl polydimethylsiloxane (PDMS) composites with the spatial alignment of carbon fibers (CFs) bridged by Al2O3 particles were fabricated by the flow field. The through-plane thermal conductivity (TPTC) of the composites with 24 vol% CFs and 47 vol% Al2O3 loading reached 38.0 W m−1 K−1. The oriented CFs bridged by Al2O3 acted as the efficient through-plane thermal conductive network. Furthermore, the effects of shape factor (b/a), spatial angle (γ) of CFs, and CF loading (Vf) on the TPTC were quantitatively discussed by steady-state finite element simulation combined with micro-computed tomography and machine learning. The positive contribution of the increased Vf to TPTC was in competition with the negative contribution of b/a and γ, both of which increased with the increase of Vf. Moreover, b/a exerted more negative effects than γ. The PDMS composites demonstrated excellent thermal stability (Td = 407.5 °C, CTE = −55.3 × 10−6 K−1), low compress modulus (1.71 MPa), and hardness (47 (Shore C)), which made them potential candidates for TIMs. This work offers a feasible method to prepare TIMs on large scale and refreshes the thermal conduction mechanism of TIMs by introducing the influencing factors (b/a and γ).
KW - Carbon fiber
KW - Finite element simulation
KW - Shape factor
KW - Spatial angle
KW - Thermal conductivity
UR - http://www.scopus.com/inward/record.url?scp=85138100823&partnerID=8YFLogxK
U2 - 10.1016/j.compscitech.2022.109717
DO - 10.1016/j.compscitech.2022.109717
M3 - 文章
AN - SCOPUS:85138100823
SN - 0266-3538
VL - 230
JO - Composites Science and Technology
JF - Composites Science and Technology
M1 - 109717
ER -