摘要
A series of fluorene-based grid molecules (so-called Grid fluorenes) have been synthesized by means of shape-supported cyclization, starting from H-shaped precursors via the alternative Friedel-Crafts reactions of fluorenols and Suzuki cross-coupling reactions with key cyclization yields up to 26%. Fluorenol approaches and nanogrids open a door to soluble one-, two-, or three-dimensional nanoporous polymers as next-generation polymer mechano-semiconductors facing a new era of consciousness.
源语言 | 英语 |
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页(从-至) | 1748-1751 |
页数 | 4 |
期刊 | Organic Letters |
卷 | 16 |
期 | 6 |
DOI | |
出版状态 | 已出版 - 21 3月 2014 |
已对外发布 | 是 |