摘要
This paper reports a study on the effects of concentration and the molecular structure of amines on the antiwear properties of TBP, TCP and TBPi, evaluated with a four‐ball machine. It was found that amines reduce the antiwear properties of P‐containing additives in the order primary>secondary>tertiary amine, and a critical amine concentration exists at which P‐containing additives lose their antiwear properties. XPS analysis indicated that the competitive adsorption of amines onto the rubbed surface causes a reduction of the antiwear properties of P‐containing additives.
源语言 | 英语 |
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页(从-至) | 283-290 |
页数 | 8 |
期刊 | Lubrication Science |
卷 | 6 |
期 | 3 |
DOI | |
出版状态 | 已出版 - 4月 1994 |
已对外发布 | 是 |