摘要
Size Exclusion Chromatography-Multi Angle Laser Light Scattering (SEC-MALL) is a novel technique for molecular weight measurement. A low molecular weight polyether glycol was taken as an example to analyze the principle of SEC-MALLS and its influencing factors. It is found that the increase in sample concentration of oligomer can reduce measurement error. The variation of dn/dc possesses little effect on the result obtained. The determination of the effective peak area in accordance with the occurrence of the differential peak versus the laser peak disappearance can obtain a result with less measurement error, and the measurement error can also be reduced through removing the data which are deviated the straight line via extrapolation the data of θ to 0° in Debye curve.
源语言 | 英语 |
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页(从-至) | 127-130 |
页数 | 4 |
期刊 | Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering |
卷 | 24 |
期 | 10 |
出版状态 | 已出版 - 10月 2008 |