Determination of molecular weight of polyether glycol by size exclusion chromatography-multi angle laser light scattering

Guang Wen Cheng, Xiao Dong Fan, Zhi Yong Zhou, Wei Tian

科研成果: 期刊稿件文章同行评审

3 引用 (Scopus)

摘要

Size Exclusion Chromatography-Multi Angle Laser Light Scattering (SEC-MALL) is a novel technique for molecular weight measurement. A low molecular weight polyether glycol was taken as an example to analyze the principle of SEC-MALLS and its influencing factors. It is found that the increase in sample concentration of oligomer can reduce measurement error. The variation of dn/dc possesses little effect on the result obtained. The determination of the effective peak area in accordance with the occurrence of the differential peak versus the laser peak disappearance can obtain a result with less measurement error, and the measurement error can also be reduced through removing the data which are deviated the straight line via extrapolation the data of θ to 0° in Debye curve.

源语言英语
页(从-至)127-130
页数4
期刊Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering
24
10
出版状态已出版 - 10月 2008

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