Abstract
Presented here are two water stable oxalate-based coordination polymers with in situ generated cyclic dipeptides, namely, (C12H16N6O2)[Zn2(C2O4)3] (SCU-63) and Mn(C2O4)(C12H14N6O2) (SCU-66). SCU-63 has a honeycomb-like layer intercalated with protonated cyclic dipeptide cations. SCU-66 has a diamondoid framework containing cyclic dipeptide ligands. The two compounds show high proton conductivity on the order of 10−3 S cm−1 at 85 °C under 98% relative humidity.
Original language | English |
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Pages (from-to) | 15288-15292 |
Number of pages | 5 |
Journal | Dalton Transactions |
Volume | 47 |
Issue number | 43 |
DOIs | |
State | Published - 2018 |
Externally published | Yes |