TY - JOUR
T1 - Urothermal in situ ligand synthesis to fabricate a metal-organic framework with (3,4)-connected tfi topology
AU - Yang, Hui
AU - Li, Tie Hu
AU - Kang, Yao
AU - Wang, Fei
PY - 2011/11
Y1 - 2011/11
N2 - A new 3D metal-organic framework [Cu(en)(ntd)](e-urea)(H2O) (1; en = 1,2-ethylenediamine, ntd = 1,4-Naphthalenedicarboxylic acid, e-urea = 2-imidazolidinone hemihydrate), has been synthesized by urothermal method. Structural analysis shows that compound 1 possesses unprecedented (3,4)-connected tfi topology. 2-imidazolidinone, one of the urea derivatives, plays multiple roles in the self-assembly of compound 1.
AB - A new 3D metal-organic framework [Cu(en)(ntd)](e-urea)(H2O) (1; en = 1,2-ethylenediamine, ntd = 1,4-Naphthalenedicarboxylic acid, e-urea = 2-imidazolidinone hemihydrate), has been synthesized by urothermal method. Structural analysis shows that compound 1 possesses unprecedented (3,4)-connected tfi topology. 2-imidazolidinone, one of the urea derivatives, plays multiple roles in the self-assembly of compound 1.
KW - 2-imidazolidinone
KW - Crystal structure
KW - Metal organic framework
KW - Topology
KW - Urothermal synthesis
UR - http://www.scopus.com/inward/record.url?scp=80053572046&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2011.07.009
DO - 10.1016/j.inoche.2011.07.009
M3 - 文章
AN - SCOPUS:80053572046
SN - 1387-7003
VL - 14
SP - 1695
EP - 1697
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 11
ER -