TY - JOUR
T1 - Unexpected One-Pot Synthesis of Diindolotriazatruxene
T2 - A Planar Electron-Rich Scaffold Toward Highly π-Extended PAHs
AU - Li, Xiangchun
AU - Wang, Chunyu
AU - Xue, Yibo
AU - Meng, Cheng
AU - Lai, Wen Yong
AU - Huang, Wei
N1 - Publisher Copyright:
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2017/12
Y1 - 2017/12
N2 - A unique planar and highly π-extended scaffold, 3,8,14,19-tetrabromo-diindolotriazatruxene (4Br-DIT), was synthesized via a facile one-pot strategy. The structure of 4Br-DIT was adequately verified by MALDI-TOF mass spectrometry, 1H and 13C NMR, and single-crystal XRD analysis. A combination of thermal, optical, and electrochemical investigation confirmed the electron-rich characteristics of the resulting diindolotriazatruxene unit, showing promise as a building block to construct highly π-extended polycyclic aromatic hydrocarbons (PAHs).
AB - A unique planar and highly π-extended scaffold, 3,8,14,19-tetrabromo-diindolotriazatruxene (4Br-DIT), was synthesized via a facile one-pot strategy. The structure of 4Br-DIT was adequately verified by MALDI-TOF mass spectrometry, 1H and 13C NMR, and single-crystal XRD analysis. A combination of thermal, optical, and electrochemical investigation confirmed the electron-rich characteristics of the resulting diindolotriazatruxene unit, showing promise as a building block to construct highly π-extended polycyclic aromatic hydrocarbons (PAHs).
KW - diindolotriazatruxene
KW - hydrocarbons
KW - optoelectronic properties
KW - polycyclic aromatic hydrocarbons
KW - structure elucidation
UR - http://www.scopus.com/inward/record.url?scp=85041122927&partnerID=8YFLogxK
U2 - 10.1002/ajoc.201700498
DO - 10.1002/ajoc.201700498
M3 - 文章
AN - SCOPUS:85041122927
SN - 2193-5807
VL - 6
SP - 1749
EP - 1754
JO - Asian Journal of Organic Chemistry
JF - Asian Journal of Organic Chemistry
IS - 12
ER -