Synthesis of silsesquioxane-contained benzoxazine and the thermal properties of its high performance polymer

Hong Xia Yan, Yuan Jia, Yi Chen Feng, Ting Ting Li

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

1 Scopus citations

Abstract

A new kind of high performance benzoxazine (BOZ) was synthesized from p-aminophenol functionalized chloropropyl polyhedral oligomeric silsesquioxane (AP-POSS), aniline and paraformaldehyde through a solvent-free process. Fourier transform infrared spectroscopy (FTIR) was employed to characterize the structure of the new BOZ resin contained POSS (POSS-BOZ). The differential scanning calorimeter (DSC) was chosen to research the curing behavior of the new resin, and the thermo gravimetric analysis (TGA) was chosen to research the thermal properties. The results show that the POSS-BOZ is successfully synthesized, and the POSS-BOZ also exhibits better thermal performance in comparison with bisphenol-A benzoxazine (bA-BOZ).

Original languageEnglish
Title of host publicationMaterials Engineering and Technology
Pages248-252
Number of pages5
DOIs
StatePublished - 2014
Event2013 International Conference on Advances and Trends in Engineering Materials and their Applications, ATEMA 2013 - , Singapore
Duration: 11 Oct 201312 Oct 2013

Publication series

NameAdvanced Materials Research
Volume849
ISSN (Print)1022-6680

Conference

Conference2013 International Conference on Advances and Trends in Engineering Materials and their Applications, ATEMA 2013
Country/TerritorySingapore
Period11/10/1312/10/13

Keywords

  • Benzoxazine
  • Polyhedral oligomeric silsesquioxane
  • Synthesis
  • Thermal properties

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