Synthesis of Donor-Acceptor Gridarenes with Tunable Electronic Structures for Synaptic Learning Memristor

Yang Yu; Linyi Bian; Yang Zhang; Zheng Liu; Yuetian Li; Ren Zhang; Ruolin Ju; Chengzhu Yin; Lei Yang; Mingdong Yi; Linghai Xie; Wei Huang

doi:10.1021/acsomega.9b00172

Synthesis of Donor-Acceptor Gridarenes with Tunable Electronic Structures for Synaptic Learning Memristor

Yang Yu, Linyi Bian, Yang Zhang, Zheng Liu, Yuetian Li, Ren Zhang, Ruolin Ju, Chengzhu Yin, Lei Yang, Mingdong Yi, Linghai Xie, Wei Huang

Institute of Flexible Electronics

Nanjing University of Posts and Telecommunications

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

A series of donor-acceptor ""-shaped gridarenes were synthesized with BT units as the crossbeam and thiophene units as the π-bridge. The donor-acceptor gridization functional effects on optoelectronic properties were then studied experimentally and computationally to provide a platform to adjust the energetics of the highest occupied molecular orbital/lowest unoccupied molecular orbital levels. Finally, G-DTh-based two-terminal memristor indium tin oxide/G-DTh:TBAPF ₆ /Al successfully realizes conventional learning processes, synaptic potentiation, and depression plasticity which are essential for neuromorphic computation.

Original language	English
Pages (from-to)	5863-5869
Number of pages	7
Journal	ACS Omega
Volume	4
Issue number	3
DOIs	https://doi.org/10.1021/acsomega.9b00172
State	Published - 26 Mar 2019

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title = "Synthesis of Donor-Acceptor Gridarenes with Tunable Electronic Structures for Synaptic Learning Memristor",

abstract = " A series of donor-acceptor {"}{"}-shaped gridarenes were synthesized with BT units as the crossbeam and thiophene units as the π-bridge. The donor-acceptor gridization functional effects on optoelectronic properties were then studied experimentally and computationally to provide a platform to adjust the energetics of the highest occupied molecular orbital/lowest unoccupied molecular orbital levels. Finally, G-DTh-based two-terminal memristor indium tin oxide/G-DTh:TBAPF 6 /Al successfully realizes conventional learning processes, synaptic potentiation, and depression plasticity which are essential for neuromorphic computation.",

author = "Yang Yu and Linyi Bian and Yang Zhang and Zheng Liu and Yuetian Li and Ren Zhang and Ruolin Ju and Chengzhu Yin and Lei Yang and Mingdong Yi and Linghai Xie and Wei Huang",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

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doi = "10.1021/acsomega.9b00172",

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T1 - Synthesis of Donor-Acceptor Gridarenes with Tunable Electronic Structures for Synaptic Learning Memristor

AU - Yu, Yang

AU - Bian, Linyi

AU - Zhang, Yang

AU - Liu, Zheng

AU - Li, Yuetian

AU - Zhang, Ren

AU - Ju, Ruolin

AU - Yin, Chengzhu

AU - Yang, Lei

AU - Yi, Mingdong

AU - Xie, Linghai

AU - Huang, Wei

PY - 2019/3/26

Y1 - 2019/3/26

N2 - A series of donor-acceptor ""-shaped gridarenes were synthesized with BT units as the crossbeam and thiophene units as the π-bridge. The donor-acceptor gridization functional effects on optoelectronic properties were then studied experimentally and computationally to provide a platform to adjust the energetics of the highest occupied molecular orbital/lowest unoccupied molecular orbital levels. Finally, G-DTh-based two-terminal memristor indium tin oxide/G-DTh:TBAPF 6 /Al successfully realizes conventional learning processes, synaptic potentiation, and depression plasticity which are essential for neuromorphic computation.

AB - A series of donor-acceptor ""-shaped gridarenes were synthesized with BT units as the crossbeam and thiophene units as the π-bridge. The donor-acceptor gridization functional effects on optoelectronic properties were then studied experimentally and computationally to provide a platform to adjust the energetics of the highest occupied molecular orbital/lowest unoccupied molecular orbital levels. Finally, G-DTh-based two-terminal memristor indium tin oxide/G-DTh:TBAPF 6 /Al successfully realizes conventional learning processes, synaptic potentiation, and depression plasticity which are essential for neuromorphic computation.

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DO - 10.1021/acsomega.9b00172

M3 - 文章

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VL - 4

SP - 5863

EP - 5869

JO - ACS Omega

JF - ACS Omega

IS - 3

ER -

Synthesis of Donor-Acceptor Gridarenes with Tunable Electronic Structures for Synaptic Learning Memristor

Abstract

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