Synthesis of 2,6-Diamino-3,5-dinitropyrazine-1-oxide

Hai Bo Li; Bi Bo Cheng; Hong Zhen Li; Fu De Nie; Jin Shan Li; Zhong Huang; Shi Jun Liu

Synthesis of 2,6-Diamino-3,5-dinitropyrazine-1-oxide

Hai Bo Li, Bi Bo Cheng, Hong Zhen Li, Fu De Nie, Jin Shan Li, Zhong Huang, Shi Jun Liu

China Academy of Engineering Physics

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

A new synthetic method of 2,6-diamino-3,5-dinitropyrazine-1-oxide (LLM-105) was discribed. LLM-105 was synthesized using 2,6-dichloropyrazine and sodium methylate as the starting materials in four steps including alkoxylation, nitration, amination and N-oxidation with total yield of 50%. The structures of intermediates and LLM-105 were determined by ¹H NMR, ¹³C NMR, IR, MS spectra and elemental analysis.

Original language	English
Pages (from-to)	112-115
Number of pages	4
Journal	Chinese Journal of Organic Chemistry
Volume	27
Issue number	1
State	Published - Jan 2007
Externally published	Yes

Keywords

2,6-diamino-3,5-dinitropyrazine-1-oxide
Energetic material
Synthesis

Cite this

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title = "Synthesis of 2,6-Diamino-3,5-dinitropyrazine-1-oxide",

abstract = "A new synthetic method of 2,6-diamino-3,5-dinitropyrazine-1-oxide (LLM-105) was discribed. LLM-105 was synthesized using 2,6-dichloropyrazine and sodium methylate as the starting materials in four steps including alkoxylation, nitration, amination and N-oxidation with total yield of 50%. The structures of intermediates and LLM-105 were determined by 1H NMR, 13C NMR, IR, MS spectra and elemental analysis.",

keywords = "2,6-diamino-3,5-dinitropyrazine-1-oxide, Energetic material, Synthesis",

author = "Li, {Hai Bo} and Cheng, {Bi Bo} and Li, {Hong Zhen} and Nie, {Fu De} and Li, {Jin Shan} and Zhong Huang and Liu, {Shi Jun}",

year = "2007",

month = jan,

language = "英语",

volume = "27",

pages = "112--115",

journal = "Chinese Journal of Organic Chemistry",

issn = "0253-2786",

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number = "1",

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TY - JOUR

T1 - Synthesis of 2,6-Diamino-3,5-dinitropyrazine-1-oxide

AU - Li, Hai Bo

AU - Cheng, Bi Bo

AU - Li, Hong Zhen

AU - Nie, Fu De

AU - Li, Jin Shan

AU - Huang, Zhong

AU - Liu, Shi Jun

PY - 2007/1

Y1 - 2007/1

N2 - A new synthetic method of 2,6-diamino-3,5-dinitropyrazine-1-oxide (LLM-105) was discribed. LLM-105 was synthesized using 2,6-dichloropyrazine and sodium methylate as the starting materials in four steps including alkoxylation, nitration, amination and N-oxidation with total yield of 50%. The structures of intermediates and LLM-105 were determined by 1H NMR, 13C NMR, IR, MS spectra and elemental analysis.

AB - A new synthetic method of 2,6-diamino-3,5-dinitropyrazine-1-oxide (LLM-105) was discribed. LLM-105 was synthesized using 2,6-dichloropyrazine and sodium methylate as the starting materials in four steps including alkoxylation, nitration, amination and N-oxidation with total yield of 50%. The structures of intermediates and LLM-105 were determined by 1H NMR, 13C NMR, IR, MS spectra and elemental analysis.

KW - 2,6-diamino-3,5-dinitropyrazine-1-oxide

KW - Energetic material

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=33846707074&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:33846707074

SN - 0253-2786

VL - 27

SP - 112

EP - 115

JO - Chinese Journal of Organic Chemistry

JF - Chinese Journal of Organic Chemistry

IS - 1

ER -

Synthesis of 2,6-Diamino-3,5-dinitropyrazine-1-oxide

Abstract

Keywords

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