Synthesis, characterization and charge storage properties of π-biindolo[2,3-b]quinoxaline for solution-processing organic transistor memory

Jianfeng Zhao, Hairong Li, Huanqun Li, Qiang Zhao, Haifeng Ling, Jiewei Li, Jinyi Lin, Linghai Xie, Zongqiong Lin, Mingdong Yi, Wei Huang

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

A novel asymmetrical biindolo[2,3-b]quinoxaline derivative (IQIQ) was prepared via the CuI catalysed C-N Ullmann coupling method and fully characterized. For comparison, two solution-processing organic transistor memory devices (A and B) were constructed. In device A with IQIQ, the parameters of large memory window (48 V) but weak on/off current ratio (∼101 at 104 s) indicated the good hole trapping ability determined by the matched HOMO level but weak endurance property of IQIQ. Meanwhile, device B with PS blended IQIQ presented not only similar large memory window but also apparently improved the hole endurance property of IQIQ determined by the blending material which intrinsically acted as the bifunctional tunneling:floating gate layer.

Original languageEnglish
Pages (from-to)255-261
Number of pages7
JournalDyes and Pigments
Volume167
DOIs
StatePublished - Aug 2019

Keywords

  • Biindolo[2,3-b]quinoxaline
  • Charge storage
  • Hole trapping
  • Organic transistor memory
  • Ullmann C-N coupling

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