Surface-initiated atom transfer radical polymerization (ATRP) of styrene from silica nanoparticles under UV irradiation

Peng Liu; Jun Tian; Weimin Liu; Qunji Xue

doi:10.1002/pi.1331

Surface-initiated atom transfer radical polymerization (ATRP) of styrene from silica nanoparticles under UV irradiation

Peng Liu, Jun Tian, Weimin Liu, Qunji Xue

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Diethyldithiocarbamyl-modified silica nanoparticles were prepared and used as macroinitiator for the surface-initiated atom transfer radical polymerization (SI-ATRP) of styrene under UV irradiation. Well-defined polymer chains were grown from the nanoparticle surfaces to yield particles composed of a silica core and a well-defined, densely grafted outer PS layer with a mass ratio of styrene to silica, or percentage grafting, of 276.3% after an UV irradiation time of 5 h.

Original language	English
Pages (from-to)	127-130
Number of pages	4
Journal	Polymer International
Volume	53
Issue number	2
DOIs	https://doi.org/10.1002/pi.1331
State	Published - Feb 2004
Externally published	Yes

Keywords

Atom transfer radical polymerization
Silica nanoparticles
Styrene
Surface-initiated
UV irradiation

Access to Document

10.1002/pi.1331

Cite this

@article{28c37f58800a4518a82cbd7266ac0f60,

title = "Surface-initiated atom transfer radical polymerization (ATRP) of styrene from silica nanoparticles under UV irradiation",

abstract = "Diethyldithiocarbamyl-modified silica nanoparticles were prepared and used as macroinitiator for the surface-initiated atom transfer radical polymerization (SI-ATRP) of styrene under UV irradiation. Well-defined polymer chains were grown from the nanoparticle surfaces to yield particles composed of a silica core and a well-defined, densely grafted outer PS layer with a mass ratio of styrene to silica, or percentage grafting, of 276.3% after an UV irradiation time of 5 h.",

keywords = "Atom transfer radical polymerization, Silica nanoparticles, Styrene, Surface-initiated, UV irradiation",

author = "Peng Liu and Jun Tian and Weimin Liu and Qunji Xue",

year = "2004",

month = feb,

doi = "10.1002/pi.1331",

language = "英语",

volume = "53",

pages = "127--130",

journal = "Polymer International",

issn = "0959-8103",

publisher = "John Wiley and Sons Ltd",

number = "2",

}

TY - JOUR

T1 - Surface-initiated atom transfer radical polymerization (ATRP) of styrene from silica nanoparticles under UV irradiation

AU - Liu, Peng

AU - Tian, Jun

AU - Liu, Weimin

AU - Xue, Qunji

PY - 2004/2

Y1 - 2004/2

N2 - Diethyldithiocarbamyl-modified silica nanoparticles were prepared and used as macroinitiator for the surface-initiated atom transfer radical polymerization (SI-ATRP) of styrene under UV irradiation. Well-defined polymer chains were grown from the nanoparticle surfaces to yield particles composed of a silica core and a well-defined, densely grafted outer PS layer with a mass ratio of styrene to silica, or percentage grafting, of 276.3% after an UV irradiation time of 5 h.

AB - Diethyldithiocarbamyl-modified silica nanoparticles were prepared and used as macroinitiator for the surface-initiated atom transfer radical polymerization (SI-ATRP) of styrene under UV irradiation. Well-defined polymer chains were grown from the nanoparticle surfaces to yield particles composed of a silica core and a well-defined, densely grafted outer PS layer with a mass ratio of styrene to silica, or percentage grafting, of 276.3% after an UV irradiation time of 5 h.

KW - Atom transfer radical polymerization

KW - Silica nanoparticles

KW - Styrene

KW - Surface-initiated

KW - UV irradiation

UR - http://www.scopus.com/inward/record.url?scp=0842313057&partnerID=8YFLogxK

U2 - 10.1002/pi.1331

DO - 10.1002/pi.1331

M3 - 文章

AN - SCOPUS:0842313057

SN - 0959-8103

VL - 53

SP - 127

EP - 130

JO - Polymer International

JF - Polymer International

IS - 2

ER -

Surface-initiated atom transfer radical polymerization (ATRP) of styrene from silica nanoparticles under UV irradiation

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this