Study on preparation of SiO2/epoxy resin hybrid materials by means of sol-gel

Jun Wei Gu; Qiu Yu Zhang; Hong Chun Li; Yu Sheng Tang; Jie Kong; Jing Dang

doi:10.1080/03602550701558033

Study on preparation of SiO₂/epoxy resin hybrid materials by means of sol-gel

Jun Wei Gu, Qiu Yu Zhang, Hong Chun Li, Yu Sheng Tang, Jie Kong, Jing Dang

School of Chemistry and Chemical Engineering

Northwestern Polytechnical University Xian

Research output: Contribution to journal › Article › peer-review

105 Scopus citations

Abstract

Silicon dioxide/epoxy resin hybrid material was prepared by means of Sol-Gel based on epoxy resin, tetraethyl orthosioate (TEOS), [H2N(CH₂)₃Si(OC₂ H₅)₃](KH-550), Methyltetrahydrophthalic anhydride (MeTHPA), dimethyl phthalate (DMP-30) and (HOCH₂ CH₂)N. The contents of TEOS, KH-550 and reacting temperature influencing on the properties of hybrid materials were studied. The behaviors of the hybrid materials were characterized by differential scanning calorimentry (DSC), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and Fourier transform-infrared ray (FT-IR) spectroscopy. The results showed that the properties of the material was optimal at approximately 3% TEOS, 2% KH-550, reacting at 60°C, and the mechanical and thermal properties were significantly improved compared with the pure epoxy resin. The dimension of SiO₂ particles was about 20 nm, and distributed homogeneously in the system.

Original language	English
Pages (from-to)	1129-1134
Number of pages	6
Journal	Polymer - Plastics Technology and Engineering
Volume	46
Issue number	12
DOIs	https://doi.org/10.1080/03602550701558033
State	Published - Dec 2007

Keywords

Epoxy resin
Hybrid materials
Sol-gel

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10.1080/03602550701558033

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title = "Study on preparation of SiO2/epoxy resin hybrid materials by means of sol-gel",

abstract = "Silicon dioxide/epoxy resin hybrid material was prepared by means of Sol-Gel based on epoxy resin, tetraethyl orthosioate (TEOS), [H2N(CH2)3Si(OC2 H5)3](KH-550), Methyltetrahydrophthalic anhydride (MeTHPA), dimethyl phthalate (DMP-30) and (HOCH2 CH2)N. The contents of TEOS, KH-550 and reacting temperature influencing on the properties of hybrid materials were studied. The behaviors of the hybrid materials were characterized by differential scanning calorimentry (DSC), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and Fourier transform-infrared ray (FT-IR) spectroscopy. The results showed that the properties of the material was optimal at approximately 3% TEOS, 2% KH-550, reacting at 60°C, and the mechanical and thermal properties were significantly improved compared with the pure epoxy resin. The dimension of SiO2 particles was about 20 nm, and distributed homogeneously in the system.",

keywords = "Epoxy resin, Hybrid materials, Sol-gel",

author = "Gu, {Jun Wei} and Zhang, {Qiu Yu} and Li, {Hong Chun} and Tang, {Yu Sheng} and Jie Kong and Jing Dang",

year = "2007",

month = dec,

doi = "10.1080/03602550701558033",

language = "英语",

volume = "46",

pages = "1129--1134",

journal = "Polymer - Plastics Technology and Engineering",

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T1 - Study on preparation of SiO2/epoxy resin hybrid materials by means of sol-gel

AU - Gu, Jun Wei

AU - Zhang, Qiu Yu

AU - Li, Hong Chun

AU - Tang, Yu Sheng

AU - Kong, Jie

AU - Dang, Jing

PY - 2007/12

Y1 - 2007/12

N2 - Silicon dioxide/epoxy resin hybrid material was prepared by means of Sol-Gel based on epoxy resin, tetraethyl orthosioate (TEOS), [H2N(CH2)3Si(OC2 H5)3](KH-550), Methyltetrahydrophthalic anhydride (MeTHPA), dimethyl phthalate (DMP-30) and (HOCH2 CH2)N. The contents of TEOS, KH-550 and reacting temperature influencing on the properties of hybrid materials were studied. The behaviors of the hybrid materials were characterized by differential scanning calorimentry (DSC), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and Fourier transform-infrared ray (FT-IR) spectroscopy. The results showed that the properties of the material was optimal at approximately 3% TEOS, 2% KH-550, reacting at 60°C, and the mechanical and thermal properties were significantly improved compared with the pure epoxy resin. The dimension of SiO2 particles was about 20 nm, and distributed homogeneously in the system.

AB - Silicon dioxide/epoxy resin hybrid material was prepared by means of Sol-Gel based on epoxy resin, tetraethyl orthosioate (TEOS), [H2N(CH2)3Si(OC2 H5)3](KH-550), Methyltetrahydrophthalic anhydride (MeTHPA), dimethyl phthalate (DMP-30) and (HOCH2 CH2)N. The contents of TEOS, KH-550 and reacting temperature influencing on the properties of hybrid materials were studied. The behaviors of the hybrid materials were characterized by differential scanning calorimentry (DSC), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and Fourier transform-infrared ray (FT-IR) spectroscopy. The results showed that the properties of the material was optimal at approximately 3% TEOS, 2% KH-550, reacting at 60°C, and the mechanical and thermal properties were significantly improved compared with the pure epoxy resin. The dimension of SiO2 particles was about 20 nm, and distributed homogeneously in the system.

KW - Epoxy resin

KW - Hybrid materials

KW - Sol-gel

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DO - 10.1080/03602550701558033

M3 - 文章

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SN - 0360-2559

VL - 46

SP - 1129

EP - 1134

JO - Polymer - Plastics Technology and Engineering

JF - Polymer - Plastics Technology and Engineering

IS - 12

ER -

Study on preparation of SiO₂/epoxy resin hybrid materials by means of sol-gel

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