Red-blood-cell-like BSA/Zn                         3                         (PO                         4                         )                         2                          hybrid particles: Preparation and application to adsorption of heavy metal ions

Baoliang Zhang; Peitao Li; Hepeng Zhang; Xiangjie Li; Lei Tian; Hai Wang; Xin Chen; Nisar Ali; Zafar Ali; Qiuyu Zhang

doi:10.1016/j.apsusc.2016.01.074

Red-blood-cell-like BSA/Zn ₃ (PO ₄ ) ₂ hybrid particles: Preparation and application to adsorption of heavy metal ions

Baoliang Zhang, Peitao Li, Hepeng Zhang, Xiangjie Li, Lei Tian, Hai Wang, Xin Chen, Nisar Ali, Zafar Ali, Qiuyu Zhang

School of Chemistry and Chemical Engineering

Northwestern Polytechnical University Xian

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

A novel kind of red-blood-cell-like bovine serum albumin (BSA)/Zn ₃ (PO ₄ ) ₂ hybrid particle is prepared at room temperature by a facile and rapid one-step method based on coordination between BSA and zinc ion. The morphology of the monodisperse hybrid particle shows oblate spheroidal type with a one sided single hole on the surface. The hybrid particle is constructed with BSA/Zn ₃ (PO ₄ ) ₂ nanoplates of 35 nm thick. The average particle size of hybrid particle is 2.3 μm, and its BET specific surface area is 146.64 cm ² /g. To clarify the evolution of BSA/Zn ₃ (PO ₄ ) ₂ hybrid particle, SEM and elemental analysis as a function of particle growth time are investigated. The formation mechanism of BSA/Zn ₃ (PO ₄ ) ₂ hybrid particle, which can be described as crystallization, coordination and self-assembly process, is illustrated in detail. The as-prepared BSA/Zn ₃ (PO ₄ ) ₂ hybrid particle is used for adsorption of Cu ²⁺ . The hybrid particle displayed excellent adsorption properties on Cu ²⁺ . The adsorption efficiency of BSA/Zn ₃ (PO ₄ ) ₂ hybrid particles at 5 min and 30 min are 86.33% and 98.9%, respectively. The maximum adsorption capacity is 6.85 mg/g. Thus, this kind of novel adsorbent shows potential application value in ultra-fast and highly efficient removal of Cu ²⁺ .

Original language	English
Pages (from-to)	328-338
Number of pages	11
Journal	Applied Surface Science
Volume	366
DOIs	https://doi.org/10.1016/j.apsusc.2016.01.074
State	Published - 15 Mar 2016

Keywords

Adsorption
BSA
Heavy metal ions
Hybrid particle
Zn (PO )

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10.1016/j.apsusc.2016.01.074

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Zhang, B., Li, P., Zhang, H., Li, X., Tian, L., Wang, H., Chen, X., Ali, N., Ali, Z., & Zhang, Q. (2016). Red-blood-cell-like BSA/Zn ₃ (PO ₄ ) ₂ hybrid particles: Preparation and application to adsorption of heavy metal ions. Applied Surface Science, 366, 328-338. https://doi.org/10.1016/j.apsusc.2016.01.074

Zhang, Baoliang ; Li, Peitao ; Zhang, Hepeng et al. / Red-blood-cell-like BSA/Zn ₃ (PO ₄ ) ₂ hybrid particles : Preparation and application to adsorption of heavy metal ions. In: Applied Surface Science. 2016 ; Vol. 366. pp. 328-338.

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title = "Red-blood-cell-like BSA/Zn 3 (PO 4 ) 2 hybrid particles: Preparation and application to adsorption of heavy metal ions",

abstract = " A novel kind of red-blood-cell-like bovine serum albumin (BSA)/Zn 3 (PO 4 ) 2 hybrid particle is prepared at room temperature by a facile and rapid one-step method based on coordination between BSA and zinc ion. The morphology of the monodisperse hybrid particle shows oblate spheroidal type with a one sided single hole on the surface. The hybrid particle is constructed with BSA/Zn 3 (PO 4 ) 2 nanoplates of 35 nm thick. The average particle size of hybrid particle is 2.3 μm, and its BET specific surface area is 146.64 cm 2 /g. To clarify the evolution of BSA/Zn 3 (PO 4 ) 2 hybrid particle, SEM and elemental analysis as a function of particle growth time are investigated. The formation mechanism of BSA/Zn 3 (PO 4 ) 2 hybrid particle, which can be described as crystallization, coordination and self-assembly process, is illustrated in detail. The as-prepared BSA/Zn 3 (PO 4 ) 2 hybrid particle is used for adsorption of Cu 2+ . The hybrid particle displayed excellent adsorption properties on Cu 2+ . The adsorption efficiency of BSA/Zn 3 (PO 4 ) 2 hybrid particles at 5 min and 30 min are 86.33% and 98.9%, respectively. The maximum adsorption capacity is 6.85 mg/g. Thus, this kind of novel adsorbent shows potential application value in ultra-fast and highly efficient removal of Cu 2+ .",

keywords = "Adsorption, BSA, Heavy metal ions, Hybrid particle, Zn (PO )",

author = "Baoliang Zhang and Peitao Li and Hepeng Zhang and Xiangjie Li and Lei Tian and Hai Wang and Xin Chen and Nisar Ali and Zafar Ali and Qiuyu Zhang",

year = "2016",

month = mar,

day = "15",

doi = "10.1016/j.apsusc.2016.01.074",

language = "英语",

volume = "366",

pages = "328--338",

journal = "Applied Surface Science",

issn = "0169-4332",

publisher = "Elsevier B.V.",

}

Zhang, B, Li, P, Zhang, H, Li, X, Tian, L, Wang, H, Chen, X, Ali, N, Ali, Z & Zhang, Q 2016, 'Red-blood-cell-like BSA/Zn ₃ (PO ₄ ) ₂ hybrid particles: Preparation and application to adsorption of heavy metal ions', Applied Surface Science, vol. 366, pp. 328-338. https://doi.org/10.1016/j.apsusc.2016.01.074

Red-blood-cell-like BSA/Zn ₃ (PO ₄ ) ₂ hybrid particles: Preparation and application to adsorption of heavy metal ions. / Zhang, Baoliang; Li, Peitao; Zhang, Hepeng et al.
In: Applied Surface Science, Vol. 366, 15.03.2016, p. 328-338.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Red-blood-cell-like BSA/Zn 3 (PO 4 ) 2 hybrid particles

T2 - Preparation and application to adsorption of heavy metal ions

AU - Zhang, Baoliang

AU - Li, Peitao

AU - Zhang, Hepeng

AU - Li, Xiangjie

AU - Tian, Lei

AU - Wang, Hai

AU - Chen, Xin

AU - Ali, Nisar

AU - Ali, Zafar

AU - Zhang, Qiuyu

PY - 2016/3/15

Y1 - 2016/3/15

N2 - A novel kind of red-blood-cell-like bovine serum albumin (BSA)/Zn 3 (PO 4 ) 2 hybrid particle is prepared at room temperature by a facile and rapid one-step method based on coordination between BSA and zinc ion. The morphology of the monodisperse hybrid particle shows oblate spheroidal type with a one sided single hole on the surface. The hybrid particle is constructed with BSA/Zn 3 (PO 4 ) 2 nanoplates of 35 nm thick. The average particle size of hybrid particle is 2.3 μm, and its BET specific surface area is 146.64 cm 2 /g. To clarify the evolution of BSA/Zn 3 (PO 4 ) 2 hybrid particle, SEM and elemental analysis as a function of particle growth time are investigated. The formation mechanism of BSA/Zn 3 (PO 4 ) 2 hybrid particle, which can be described as crystallization, coordination and self-assembly process, is illustrated in detail. The as-prepared BSA/Zn 3 (PO 4 ) 2 hybrid particle is used for adsorption of Cu 2+ . The hybrid particle displayed excellent adsorption properties on Cu 2+ . The adsorption efficiency of BSA/Zn 3 (PO 4 ) 2 hybrid particles at 5 min and 30 min are 86.33% and 98.9%, respectively. The maximum adsorption capacity is 6.85 mg/g. Thus, this kind of novel adsorbent shows potential application value in ultra-fast and highly efficient removal of Cu 2+ .

AB - A novel kind of red-blood-cell-like bovine serum albumin (BSA)/Zn 3 (PO 4 ) 2 hybrid particle is prepared at room temperature by a facile and rapid one-step method based on coordination between BSA and zinc ion. The morphology of the monodisperse hybrid particle shows oblate spheroidal type with a one sided single hole on the surface. The hybrid particle is constructed with BSA/Zn 3 (PO 4 ) 2 nanoplates of 35 nm thick. The average particle size of hybrid particle is 2.3 μm, and its BET specific surface area is 146.64 cm 2 /g. To clarify the evolution of BSA/Zn 3 (PO 4 ) 2 hybrid particle, SEM and elemental analysis as a function of particle growth time are investigated. The formation mechanism of BSA/Zn 3 (PO 4 ) 2 hybrid particle, which can be described as crystallization, coordination and self-assembly process, is illustrated in detail. The as-prepared BSA/Zn 3 (PO 4 ) 2 hybrid particle is used for adsorption of Cu 2+ . The hybrid particle displayed excellent adsorption properties on Cu 2+ . The adsorption efficiency of BSA/Zn 3 (PO 4 ) 2 hybrid particles at 5 min and 30 min are 86.33% and 98.9%, respectively. The maximum adsorption capacity is 6.85 mg/g. Thus, this kind of novel adsorbent shows potential application value in ultra-fast and highly efficient removal of Cu 2+ .

KW - Adsorption

KW - BSA

KW - Heavy metal ions

KW - Hybrid particle

KW - Zn (PO )

UR - http://www.scopus.com/inward/record.url?scp=84958282667&partnerID=8YFLogxK

U2 - 10.1016/j.apsusc.2016.01.074

DO - 10.1016/j.apsusc.2016.01.074

M3 - 文章

AN - SCOPUS:84958282667

SN - 0169-4332

VL - 366

SP - 328

EP - 338

JO - Applied Surface Science

JF - Applied Surface Science

ER -

Zhang B, Li P, Zhang H, Li X, Tian L, Wang H et al. Red-blood-cell-like BSA/Zn ₃ (PO ₄ ) ₂ hybrid particles: Preparation and application to adsorption of heavy metal ions. Applied Surface Science. 2016 Mar 15;366:328-338. doi: 10.1016/j.apsusc.2016.01.074

Red-blood-cell-like BSA/Zn ₃ (PO ₄ ) ₂ hybrid particles: Preparation and application to adsorption of heavy metal ions

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Keywords

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