Properties and structures of novel cyanate ester/organic rectorite nanocomposites

Li Yuan; Aijuan Gu; Guozheng Liang; Xiaoyan Ma; Chao Lin; Feng Chen

doi:10.1002/pen.23198

Properties and structures of novel cyanate ester/organic rectorite nanocomposites

Li Yuan, Aijuan Gu, Guozheng Liang, Xiaoyan Ma, Chao Lin, Feng Chen

School of Chemistry and Chemical Engineering

Soochow University

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Organic rectorite (OREC) was applied to bisphenol A dicyanate ester (BADCy) resin to develop a novel BADCy/OREC system. The influence of OREC on the reactivity of BADCy was discussed. The morphologies of cured BADCy/OREC systems were investigated by X-ray diffraction (XRD), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). The static and dynamic mechanical properties as well as the hot water resistance of cured BADCy/OREC systems were evaluated. Results indicate that the addition of OREC can catalyze the reaction of BDACy resin. The intercalated structure and exfoliated structure of silicate platelets may be formed in the cured BADCy/OREC composites. The suitable amount of OREC can improve the flexural strength, the impact resistance and the hot water resistance of cured BADCy. OREC can maintain the glass transition temperature (Tg) and have slight influence on the dielectric property of cured BADCy.

Original language	English
Pages (from-to)	2443-2453
Number of pages	11
Journal	Polymer Engineering and Science
Volume	52
Issue number	11
DOIs	https://doi.org/10.1002/pen.23198
State	Published - Nov 2012

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title = "Properties and structures of novel cyanate ester/organic rectorite nanocomposites",

abstract = "Organic rectorite (OREC) was applied to bisphenol A dicyanate ester (BADCy) resin to develop a novel BADCy/OREC system. The influence of OREC on the reactivity of BADCy was discussed. The morphologies of cured BADCy/OREC systems were investigated by X-ray diffraction (XRD), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). The static and dynamic mechanical properties as well as the hot water resistance of cured BADCy/OREC systems were evaluated. Results indicate that the addition of OREC can catalyze the reaction of BDACy resin. The intercalated structure and exfoliated structure of silicate platelets may be formed in the cured BADCy/OREC composites. The suitable amount of OREC can improve the flexural strength, the impact resistance and the hot water resistance of cured BADCy. OREC can maintain the glass transition temperature (Tg) and have slight influence on the dielectric property of cured BADCy.",

author = "Li Yuan and Aijuan Gu and Guozheng Liang and Xiaoyan Ma and Chao Lin and Feng Chen",

year = "2012",

month = nov,

doi = "10.1002/pen.23198",

language = "英语",

volume = "52",

pages = "2443--2453",

journal = "Polymer Engineering and Science",

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publisher = "John Wiley and Sons Inc",

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TY - JOUR

T1 - Properties and structures of novel cyanate ester/organic rectorite nanocomposites

AU - Yuan, Li

AU - Gu, Aijuan

AU - Liang, Guozheng

AU - Ma, Xiaoyan

AU - Lin, Chao

AU - Chen, Feng

PY - 2012/11

Y1 - 2012/11

N2 - Organic rectorite (OREC) was applied to bisphenol A dicyanate ester (BADCy) resin to develop a novel BADCy/OREC system. The influence of OREC on the reactivity of BADCy was discussed. The morphologies of cured BADCy/OREC systems were investigated by X-ray diffraction (XRD), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). The static and dynamic mechanical properties as well as the hot water resistance of cured BADCy/OREC systems were evaluated. Results indicate that the addition of OREC can catalyze the reaction of BDACy resin. The intercalated structure and exfoliated structure of silicate platelets may be formed in the cured BADCy/OREC composites. The suitable amount of OREC can improve the flexural strength, the impact resistance and the hot water resistance of cured BADCy. OREC can maintain the glass transition temperature (Tg) and have slight influence on the dielectric property of cured BADCy.

AB - Organic rectorite (OREC) was applied to bisphenol A dicyanate ester (BADCy) resin to develop a novel BADCy/OREC system. The influence of OREC on the reactivity of BADCy was discussed. The morphologies of cured BADCy/OREC systems were investigated by X-ray diffraction (XRD), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). The static and dynamic mechanical properties as well as the hot water resistance of cured BADCy/OREC systems were evaluated. Results indicate that the addition of OREC can catalyze the reaction of BDACy resin. The intercalated structure and exfoliated structure of silicate platelets may be formed in the cured BADCy/OREC composites. The suitable amount of OREC can improve the flexural strength, the impact resistance and the hot water resistance of cured BADCy. OREC can maintain the glass transition temperature (Tg) and have slight influence on the dielectric property of cured BADCy.

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U2 - 10.1002/pen.23198

DO - 10.1002/pen.23198

M3 - 文章

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SN - 0032-3888

VL - 52

SP - 2443

EP - 2453

JO - Polymer Engineering and Science

JF - Polymer Engineering and Science

IS - 11

ER -

Properties and structures of novel cyanate ester/organic rectorite nanocomposites

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