Preparation, infrared emissivity, and dielectric and microwave absorption properties of Fe-doped ZnO powder

Xiaolei Su; Yan Jia; Xiaoqin Liu; Junbo Wang; Jie Xu; Xinhai He; Chong Fu; Songtao Liu

doi:10.1007/s11664-014-3218-y

Preparation, infrared emissivity, and dielectric and microwave absorption properties of Fe-doped ZnO powder

Xiaolei Su, Yan Jia, Xiaoqin Liu, Junbo Wang, Jie Xu, Xinhai He, Chong Fu, Songtao Liu

Xi'an Polytechnic University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Fe-doped ZnO powders have been synthesized by the coprecipitation method using zinc nitrate [Zn(NO₃)₂·6H₂O] as starting material, urea [CO(NH₂)₂] as precipitator, and ferric nitrate [Fe(NO₃)₃·9H₂O] as doping source. The microstructure of the prepared powders has been characterized by x-ray diffraction and scanning electron microscopy. Results show that, when the molar ratio of Fe to (Zn + Fe) was less than 0.09, the prepared powder was ZnO(Fe) solid solution, and the ZnFe₂O₄ impurity phase appeared when the Fe doping content was further increased. The electric permittivity in the frequency range of 8.2 GHz to 12.4 GHz and the average infrared emissivity in the wavelength range of 8 μm to 14 μm have been determined for the prepared powders. The average infrared emissivity decreased with increasing Fe doping content. The real (ε) and imaginary part (ε) of the permittivity of the prepared powders showed opposite trends. When the molar ratio of Fe to (Zn + Fe) was 0.03, the prepared Fe-doped ZnO powder demonstrated the best microwave absorption in the frequency range of 8.2 GHz to 12.4 GHz.

Original language	English
Pages (from-to)	3942-3948
Number of pages	7
Journal	Journal of Electronic Materials
Volume	43
Issue number	11
DOIs	https://doi.org/10.1007/s11664-014-3218-y
State	Published - 1 Nov 2014
Externally published	Yes

Keywords

electrical properties
Oxides
x-ray diffraction

Access to Document

10.1007/s11664-014-3218-y

Cite this

@article{be0e890186fa44f5bf2ae23e6369ef5b,

title = "Preparation, infrared emissivity, and dielectric and microwave absorption properties of Fe-doped ZnO powder",

abstract = "Fe-doped ZnO powders have been synthesized by the coprecipitation method using zinc nitrate [Zn(NO3)2·6H2O] as starting material, urea [CO(NH2)2] as precipitator, and ferric nitrate [Fe(NO3)3·9H2O] as doping source. The microstructure of the prepared powders has been characterized by x-ray diffraction and scanning electron microscopy. Results show that, when the molar ratio of Fe to (Zn + Fe) was less than 0.09, the prepared powder was ZnO(Fe) solid solution, and the ZnFe2O4 impurity phase appeared when the Fe doping content was further increased. The electric permittivity in the frequency range of 8.2 GHz to 12.4 GHz and the average infrared emissivity in the wavelength range of 8 μm to 14 μm have been determined for the prepared powders. The average infrared emissivity decreased with increasing Fe doping content. The real (ε) and imaginary part (ε) of the permittivity of the prepared powders showed opposite trends. When the molar ratio of Fe to (Zn + Fe) was 0.03, the prepared Fe-doped ZnO powder demonstrated the best microwave absorption in the frequency range of 8.2 GHz to 12.4 GHz.",

keywords = "electrical properties, Oxides, x-ray diffraction",

author = "Xiaolei Su and Yan Jia and Xiaoqin Liu and Junbo Wang and Jie Xu and Xinhai He and Chong Fu and Songtao Liu",

note = "Publisher Copyright: {\textcopyright} 2014 TMS.",

year = "2014",

month = nov,

day = "1",

doi = "10.1007/s11664-014-3218-y",

language = "英语",

volume = "43",

pages = "3942--3948",

journal = "Journal of Electronic Materials",

issn = "0361-5235",

publisher = "Springer New York",

number = "11",

}

TY - JOUR

T1 - Preparation, infrared emissivity, and dielectric and microwave absorption properties of Fe-doped ZnO powder

AU - Su, Xiaolei

AU - Jia, Yan

AU - Liu, Xiaoqin

AU - Wang, Junbo

AU - Xu, Jie

AU - He, Xinhai

AU - Fu, Chong

AU - Liu, Songtao

PY - 2014/11/1

Y1 - 2014/11/1

N2 - Fe-doped ZnO powders have been synthesized by the coprecipitation method using zinc nitrate [Zn(NO3)2·6H2O] as starting material, urea [CO(NH2)2] as precipitator, and ferric nitrate [Fe(NO3)3·9H2O] as doping source. The microstructure of the prepared powders has been characterized by x-ray diffraction and scanning electron microscopy. Results show that, when the molar ratio of Fe to (Zn + Fe) was less than 0.09, the prepared powder was ZnO(Fe) solid solution, and the ZnFe2O4 impurity phase appeared when the Fe doping content was further increased. The electric permittivity in the frequency range of 8.2 GHz to 12.4 GHz and the average infrared emissivity in the wavelength range of 8 μm to 14 μm have been determined for the prepared powders. The average infrared emissivity decreased with increasing Fe doping content. The real (ε) and imaginary part (ε) of the permittivity of the prepared powders showed opposite trends. When the molar ratio of Fe to (Zn + Fe) was 0.03, the prepared Fe-doped ZnO powder demonstrated the best microwave absorption in the frequency range of 8.2 GHz to 12.4 GHz.

AB - Fe-doped ZnO powders have been synthesized by the coprecipitation method using zinc nitrate [Zn(NO3)2·6H2O] as starting material, urea [CO(NH2)2] as precipitator, and ferric nitrate [Fe(NO3)3·9H2O] as doping source. The microstructure of the prepared powders has been characterized by x-ray diffraction and scanning electron microscopy. Results show that, when the molar ratio of Fe to (Zn + Fe) was less than 0.09, the prepared powder was ZnO(Fe) solid solution, and the ZnFe2O4 impurity phase appeared when the Fe doping content was further increased. The electric permittivity in the frequency range of 8.2 GHz to 12.4 GHz and the average infrared emissivity in the wavelength range of 8 μm to 14 μm have been determined for the prepared powders. The average infrared emissivity decreased with increasing Fe doping content. The real (ε) and imaginary part (ε) of the permittivity of the prepared powders showed opposite trends. When the molar ratio of Fe to (Zn + Fe) was 0.03, the prepared Fe-doped ZnO powder demonstrated the best microwave absorption in the frequency range of 8.2 GHz to 12.4 GHz.

KW - electrical properties

KW - Oxides

KW - x-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=84907712326&partnerID=8YFLogxK

U2 - 10.1007/s11664-014-3218-y

DO - 10.1007/s11664-014-3218-y

M3 - 文章

AN - SCOPUS:84907712326

SN - 0361-5235

VL - 43

SP - 3942

EP - 3948

JO - Journal of Electronic Materials

JF - Journal of Electronic Materials

IS - 11

ER -

Preparation, infrared emissivity, and dielectric and microwave absorption properties of Fe-doped ZnO powder

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this