TY - JOUR
T1 - Oxidation resistance and mechanical characterization of silicide coatings on the Nb-18Ti-14Si-9Al alloy
AU - Sun, Zhiping
AU - Tian, Xiaodong
AU - Guo, Xiping
AU - Yin, Mengjiao
AU - Zhang, Fengying
AU - Zhang, Xuemin
N1 - Publisher Copyright:
© 2017 Elsevier Ltd
PY - 2017/12
Y1 - 2017/12
N2 - The Nb-Si alloys are attractive candidate for more advanced aircraft engines, however their oxidation resistances are poor. In this work, silicide coatings were prepared on the Nb-18Ti-14Si-9Al substrate, and we present the concern of this Nb-Si alloy with high Al content, and focused the modification effect of Al on NbSi2 coatings. It is found that composition of the substrate alloy have an essential effect on coatings, which is composed of (Nb,Ti)Si2 outer layer and (Nb,Ti)Si2 + (Nb,Ti)3Si5Al2 inner layer. Underneath inner layer, NbAl3 is formed and surrounded by Nb5Si3. Beyond fracture toughness test, the coating still preserved the integrity and tightly adhered to substrate, no cracks nucleated between substrate and the coating. After oxidation at 1250 °C for 50 h, the mass gain of substrate and silicide coating is 398.85 mg/cm2 and 2.34 mg/cm2 respectively. The excellent oxidation resistance of the coating is proved to benefit from modification effects of high Al in the substrate.
AB - The Nb-Si alloys are attractive candidate for more advanced aircraft engines, however their oxidation resistances are poor. In this work, silicide coatings were prepared on the Nb-18Ti-14Si-9Al substrate, and we present the concern of this Nb-Si alloy with high Al content, and focused the modification effect of Al on NbSi2 coatings. It is found that composition of the substrate alloy have an essential effect on coatings, which is composed of (Nb,Ti)Si2 outer layer and (Nb,Ti)Si2 + (Nb,Ti)3Si5Al2 inner layer. Underneath inner layer, NbAl3 is formed and surrounded by Nb5Si3. Beyond fracture toughness test, the coating still preserved the integrity and tightly adhered to substrate, no cracks nucleated between substrate and the coating. After oxidation at 1250 °C for 50 h, the mass gain of substrate and silicide coating is 398.85 mg/cm2 and 2.34 mg/cm2 respectively. The excellent oxidation resistance of the coating is proved to benefit from modification effects of high Al in the substrate.
KW - Al modification
KW - Nb-Ti-Si-Al alloy
KW - Oxidation resistance
KW - Silicide coating
UR - http://www.scopus.com/inward/record.url?scp=85026665814&partnerID=8YFLogxK
U2 - 10.1016/j.ijrmhm.2017.07.016
DO - 10.1016/j.ijrmhm.2017.07.016
M3 - 文章
AN - SCOPUS:85026665814
SN - 0263-4368
VL - 69
SP - 18
EP - 26
JO - International Journal of Refractory Metals and Hard Materials
JF - International Journal of Refractory Metals and Hard Materials
ER -