One-pot synthesis of benzoxaborole derivatives from the palladium-catalyzed cross-coupling reaction of alkoxydiboron with unprotected o-bromobenzylalcohols

Jianan Zhu; Ying Wei; Dongqing Lin; Changjin Ou; Linghai Xie; Yu Zhao; Wei Huang

doi:10.1039/c5ob01781e

One-pot synthesis of benzoxaborole derivatives from the palladium-catalyzed cross-coupling reaction of alkoxydiboron with unprotected o-bromobenzylalcohols

Jianan Zhu, Ying Wei, Dongqing Lin, Changjin Ou, Linghai Xie, Yu Zhao, Wei Huang

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Under very mild conditions, functionalized benzoxaborole derivatives were prepared in good to excellent yields via a palladium-catalyzed Miyaura borylation reaction of readily available unprotected o-bromobenzylalcohols, and bis(pinacolato)diboron (B₂pin₂) without the assistance of an acid. Blue-light-emitting materials based on spiro benzoxaborole building blocks have been obtained with potential applications in organic electronics and biomedicine.

Original language	English
Pages (from-to)	11362-11368
Number of pages	7
Journal	Organic and Biomolecular Chemistry
Volume	13
Issue number	46
DOIs	https://doi.org/10.1039/c5ob01781e
State	Published - 24 Sep 2015
Externally published	Yes

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title = "One-pot synthesis of benzoxaborole derivatives from the palladium-catalyzed cross-coupling reaction of alkoxydiboron with unprotected o-bromobenzylalcohols",

abstract = "Under very mild conditions, functionalized benzoxaborole derivatives were prepared in good to excellent yields via a palladium-catalyzed Miyaura borylation reaction of readily available unprotected o-bromobenzylalcohols, and bis(pinacolato)diboron (B2pin2) without the assistance of an acid. Blue-light-emitting materials based on spiro benzoxaborole building blocks have been obtained with potential applications in organic electronics and biomedicine.",

author = "Jianan Zhu and Ying Wei and Dongqing Lin and Changjin Ou and Linghai Xie and Yu Zhao and Wei Huang",

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year = "2015",

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doi = "10.1039/c5ob01781e",

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T1 - One-pot synthesis of benzoxaborole derivatives from the palladium-catalyzed cross-coupling reaction of alkoxydiboron with unprotected o-bromobenzylalcohols

AU - Zhu, Jianan

AU - Wei, Ying

AU - Lin, Dongqing

AU - Ou, Changjin

AU - Xie, Linghai

AU - Zhao, Yu

AU - Huang, Wei

PY - 2015/9/24

Y1 - 2015/9/24

N2 - Under very mild conditions, functionalized benzoxaborole derivatives were prepared in good to excellent yields via a palladium-catalyzed Miyaura borylation reaction of readily available unprotected o-bromobenzylalcohols, and bis(pinacolato)diboron (B2pin2) without the assistance of an acid. Blue-light-emitting materials based on spiro benzoxaborole building blocks have been obtained with potential applications in organic electronics and biomedicine.

AB - Under very mild conditions, functionalized benzoxaborole derivatives were prepared in good to excellent yields via a palladium-catalyzed Miyaura borylation reaction of readily available unprotected o-bromobenzylalcohols, and bis(pinacolato)diboron (B2pin2) without the assistance of an acid. Blue-light-emitting materials based on spiro benzoxaborole building blocks have been obtained with potential applications in organic electronics and biomedicine.

UR - http://www.scopus.com/inward/record.url?scp=84947803698&partnerID=8YFLogxK

U2 - 10.1039/c5ob01781e

DO - 10.1039/c5ob01781e

M3 - 文章

AN - SCOPUS:84947803698

SN - 1477-0520

VL - 13

SP - 11362

EP - 11368

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 46

ER -

One-pot synthesis of benzoxaborole derivatives from the palladium-catalyzed cross-coupling reaction of alkoxydiboron with unprotected o-bromobenzylalcohols

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