Nanofiltration Membranes with Metal Cation-Immobilized Aminophosphonate Networks for Efficient Heavy Metal Ion Removal and Organic Dye Degradation

Modifications to the surface of polymeric membranes to integrate supplemental properties like surface charge or catalytic activity are the cornerstone of the membrane process advancement to effectuate improvements in functionality and selectivity. Herein, a new approach is demonstrated to construct nanofiltration membranes with a metal-organic coordinated selective layer. Polyethylenimine (PEI) was integrated with phosphite linkages to form a characteristic aminophosphonate ester polymer based on the Kabachnik-Fields reaction, and a thin polymer layer was deposited on an ultrafiltration (UF) membrane to form the aminophosphonate networks surface-modified membranes. The aminophosphonate polymer interlayer facilitated the immobilization of metal cation moieties through the strong coordinative chemical bonding with the amino groups and phosphite moieties. Typically, the incorporated Fe³⁺ strengthened the membranes' electropositivity leading to excellent heavy metal ion removal (>98%) and efficient organic dye separation (>99.8%). Meanwhile, the strategy also enabled the embedment of a photocatalytic layer comprising nanoneedle-like α-FeOOH that endowed the membrane with high photo-Fenton activity for organic dye mineralization. Subsequently, the α-FeOOH-embedded membrane afforded the photocatalytic self-cleaning potentiality for organic fouling mitigation. This contribution underscores the prospect of advancing the integration of metal-specific functionalities and the membrane process for advanced membrane technologies in water treatment.