MOF-derived surface modified Ni nanoparticles as an efficient catalyst for the hydrogen evolution reaction

Teng Wang; Qianyu Zhou; Xiaojuan Wang; Jie Zheng; Xingguo Li

doi:10.1039/C5TA04001A

MOF-derived surface modified Ni nanoparticles as an efficient catalyst for the hydrogen evolution reaction

Teng Wang, Qianyu Zhou, Xiaojuan Wang, Jie Zheng, Xingguo Li

Peking University

Research output: Contribution to journal › Article › peer-review

153 Scopus citations

Abstract

Pyrolysis of a Ni based metal organic framework in NH₃ yields Ni nanoparticles with surface nitridation together with thin carbon coating layers. The subtle surface modification significantly improves the catalytic performance for the hydrogen evolution reaction (HER). The surface modified Ni nanoparticles show a low overpotential of only 88 mV at a current density of 20 mA cm^-2, which is one of the most efficient HER catalysts based on metallic Ni reported so far. The results suggest that controlled pyrolysis of MOFs is an effective method to prepare highly efficient noble metal free HER catalysts.

Original language	English
Pages (from-to)	16435-16439
Number of pages	5
Journal	Journal of Materials Chemistry A
Volume	3
Issue number	32
DOIs	https://doi.org/10.1039/C5TA04001A
State	Published - 28 Aug 2015
Externally published	Yes

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title = "MOF-derived surface modified Ni nanoparticles as an efficient catalyst for the hydrogen evolution reaction",

abstract = "Pyrolysis of a Ni based metal organic framework in NH3 yields Ni nanoparticles with surface nitridation together with thin carbon coating layers. The subtle surface modification significantly improves the catalytic performance for the hydrogen evolution reaction (HER). The surface modified Ni nanoparticles show a low overpotential of only 88 mV at a current density of 20 mA cm-2, which is one of the most efficient HER catalysts based on metallic Ni reported so far. The results suggest that controlled pyrolysis of MOFs is an effective method to prepare highly efficient noble metal free HER catalysts.",

author = "Teng Wang and Qianyu Zhou and Xiaojuan Wang and Jie Zheng and Xingguo Li",

note = "Publisher Copyright: {\textcopyright} 2015 The Royal Society of Chemistry.",

year = "2015",

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doi = "10.1039/C5TA04001A",

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T1 - MOF-derived surface modified Ni nanoparticles as an efficient catalyst for the hydrogen evolution reaction

AU - Wang, Teng

AU - Zhou, Qianyu

AU - Wang, Xiaojuan

AU - Zheng, Jie

AU - Li, Xingguo

PY - 2015/8/28

Y1 - 2015/8/28

N2 - Pyrolysis of a Ni based metal organic framework in NH3 yields Ni nanoparticles with surface nitridation together with thin carbon coating layers. The subtle surface modification significantly improves the catalytic performance for the hydrogen evolution reaction (HER). The surface modified Ni nanoparticles show a low overpotential of only 88 mV at a current density of 20 mA cm-2, which is one of the most efficient HER catalysts based on metallic Ni reported so far. The results suggest that controlled pyrolysis of MOFs is an effective method to prepare highly efficient noble metal free HER catalysts.

AB - Pyrolysis of a Ni based metal organic framework in NH3 yields Ni nanoparticles with surface nitridation together with thin carbon coating layers. The subtle surface modification significantly improves the catalytic performance for the hydrogen evolution reaction (HER). The surface modified Ni nanoparticles show a low overpotential of only 88 mV at a current density of 20 mA cm-2, which is one of the most efficient HER catalysts based on metallic Ni reported so far. The results suggest that controlled pyrolysis of MOFs is an effective method to prepare highly efficient noble metal free HER catalysts.

UR - http://www.scopus.com/inward/record.url?scp=84938591081&partnerID=8YFLogxK

U2 - 10.1039/C5TA04001A

DO - 10.1039/C5TA04001A

M3 - 文章

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SN - 2050-7488

VL - 3

SP - 16435

EP - 16439

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 32

ER -

MOF-derived surface modified Ni nanoparticles as an efficient catalyst for the hydrogen evolution reaction

Abstract

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