Macrospirocyclic oligomers based on carbazole and fluorene

Yu Lu, Yu Zhou, Yi Wu Quan, Qing Min Chen, Run Feng Chen, Zhi Yong Zhang, Qu Li Fan, Wei Huang, Jian Fu Ding

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

Monodisperse macrospirocyclic oligomers were prepared using self-condensation of the Friedel-Crafts reaction. Through the C-9s of the central fluorene units of four surrounding oligofluorenes, four carbazole units are connected in a series to form a macrocyclic core. These rodlike oligofluorenes form a rigid three-dimensional structure, affording the resulting macrocyclics a high steric hindrance for close interchain packing.

Original languageEnglish
Pages (from-to)200-203
Number of pages4
JournalOrganic Letters
Volume13
Issue number2
DOIs
StatePublished - 21 Jan 2011
Externally publishedYes

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