TY - JOUR
T1 - Long-Chain Hyperbranched Polymers
T2 - Synthesis, Properties, and Applications
AU - Mu, Bin
AU - Liu, Tingting
AU - Tian, Wei
N1 - Publisher Copyright:
© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2019/9/1
Y1 - 2019/9/1
N2 - By combining the virtues of conventional linear and hyperbranched polymers, long-chain hyperbranched polymers (LCHBPs) have attracted great attention. Therefore, a comprehensive summary of the research progress of LCHBPs is presented, with a particular focus on their synthetic strategies, unique properties, and potential applications. The synthetic methodologies are rationalized into four main classes according to their construction process or mechanism, namely ABx (x ≥ 2), A2 + Bx (x ≥ 3), AB + ABx (x ≥ 2), and self-condensing vinyl polymerization. Some of their rheological properties, self-assembly behavior, and stimuli-response features are then discussed. Finally, the emergent applications including biomedicine, electrical conductivity, chemical sensing, and catalyst carrier, are outlined. It is anticipated that this review will stimulate more inspiration for advancing the development of this novel kind of LCHBP.
AB - By combining the virtues of conventional linear and hyperbranched polymers, long-chain hyperbranched polymers (LCHBPs) have attracted great attention. Therefore, a comprehensive summary of the research progress of LCHBPs is presented, with a particular focus on their synthetic strategies, unique properties, and potential applications. The synthetic methodologies are rationalized into four main classes according to their construction process or mechanism, namely ABx (x ≥ 2), A2 + Bx (x ≥ 3), AB + ABx (x ≥ 2), and self-condensing vinyl polymerization. Some of their rheological properties, self-assembly behavior, and stimuli-response features are then discussed. Finally, the emergent applications including biomedicine, electrical conductivity, chemical sensing, and catalyst carrier, are outlined. It is anticipated that this review will stimulate more inspiration for advancing the development of this novel kind of LCHBP.
KW - hyperbranched polymers
KW - long-chain hyperbranched polymers
KW - macromonomers
KW - synthesis
UR - http://www.scopus.com/inward/record.url?scp=85053409418&partnerID=8YFLogxK
U2 - 10.1002/marc.201800471
DO - 10.1002/marc.201800471
M3 - 文献综述
C2 - 30277631
AN - SCOPUS:85053409418
SN - 1022-1336
VL - 40
JO - Macromolecular Rapid Communications
JF - Macromolecular Rapid Communications
IS - 17
M1 - 1800471
ER -