Interconversion and decomposition of furanones

Zhi Ping Xu; Chup Yew Mok; Wee Shong Chin; Hsing Hua Huang; Sheng Li; Wei Huang

doi:10.1039/a810028d

Interconversion and decomposition of furanones

Zhi Ping Xu, Chup Yew Mok, Wee Shong Chin, Hsing Hua Huang, Sheng Li, Wei Huang

National University of Singapore

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The interconversion and decomposition of furan-2(3H)- and -2(5H)-one and their methylated derivatives were studied by following the changes in their photoelectron spectra during pyrolysis. Interconversion occurred at 300-400°C and decomposition at around 600°C giving CO and acrolein as the only products for the unsubstituted furanones. The experimental results suggest that decarbonylation takes place through the 2(3H) form as the common precursor.

Original language	English
Pages (from-to)	725-729
Number of pages	5
Journal	Journal of the Chemical Society. Perkin Transactions 2
Issue number	4
DOIs	https://doi.org/10.1039/a810028d
State	Published - Apr 1999
Externally published	Yes

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title = "Interconversion and decomposition of furanones",

abstract = "The interconversion and decomposition of furan-2(3H)- and -2(5H)-one and their methylated derivatives were studied by following the changes in their photoelectron spectra during pyrolysis. Interconversion occurred at 300-400°C and decomposition at around 600°C giving CO and acrolein as the only products for the unsubstituted furanones. The experimental results suggest that decarbonylation takes place through the 2(3H) form as the common precursor.",

author = "Xu, {Zhi Ping} and Mok, {Chup Yew} and Chin, {Wee Shong} and Huang, {Hsing Hua} and Sheng Li and Wei Huang",

year = "1999",

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doi = "10.1039/a810028d",

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pages = "725--729",

journal = "Journal of the Chemical Society. Perkin Transactions 2",

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T1 - Interconversion and decomposition of furanones

AU - Xu, Zhi Ping

AU - Mok, Chup Yew

AU - Chin, Wee Shong

AU - Huang, Hsing Hua

AU - Li, Sheng

AU - Huang, Wei

PY - 1999/4

Y1 - 1999/4

N2 - The interconversion and decomposition of furan-2(3H)- and -2(5H)-one and their methylated derivatives were studied by following the changes in their photoelectron spectra during pyrolysis. Interconversion occurred at 300-400°C and decomposition at around 600°C giving CO and acrolein as the only products for the unsubstituted furanones. The experimental results suggest that decarbonylation takes place through the 2(3H) form as the common precursor.

AB - The interconversion and decomposition of furan-2(3H)- and -2(5H)-one and their methylated derivatives were studied by following the changes in their photoelectron spectra during pyrolysis. Interconversion occurred at 300-400°C and decomposition at around 600°C giving CO and acrolein as the only products for the unsubstituted furanones. The experimental results suggest that decarbonylation takes place through the 2(3H) form as the common precursor.

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U2 - 10.1039/a810028d

DO - 10.1039/a810028d

M3 - 文章

AN - SCOPUS:0042048223

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JO - Journal of the Chemical Society. Perkin Transactions 2

JF - Journal of the Chemical Society. Perkin Transactions 2

IS - 4

ER -

Interconversion and decomposition of furanones

Abstract

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