Insight into the oxidation behavior and excellent internal oxidation and nitridation resistance of Fe71.5-x(Ni, Cr, Ti)28.5Alx complex concentrated alloys by advanced characterization

Jiang Ju, Yimeng Zhao, Zhao Shen, Kai Chen, Bo Xiao, Xia Li, Dongqing Qi, Yilu Zhao, Jun Wang, Baode Sun, Tao Yang

Research output: Contribution to journalArticlepeer-review

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Abstract

For precipitate-strengthened alloys, the decomposition of the precipitates at the subsurface during high-temperature oxidation is detrimental to mechanical properties. In this study, we adjusted Al concentrations in Fe71.5-x(Ni, Cr, Ti)28.5Alx (x = 8, 12, and 16 at%) complex concentrated alloys (CCAs) to precipitate elongated cuboidal L21 with higher density and Al concentration, as well as reduced inter-precipitate spacing. This is more conducive to the rapid diffusion of Al to the matrix and grain boundaries, promoting the formation of a continuous and compact Al2O3 layer with random crystallographic orientation at 800 °C in air. This not only inhibits the further decomposition of the L21 phase but also avoids internal oxidation and nitridation.

Original languageEnglish
Article number112544
JournalCorrosion Science
Volume241
DOIs
StatePublished - Dec 2024
Externally publishedYes

Keywords

  • Complex concentrated alloy
  • Diffusion
  • High-temperature oxidation
  • Multi-scale characterization
  • Nitridation

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