Abstract
We report a new type of zwitterionic gelator, which cannot only gelate base lubricating oils by supramolecular self-assembly, but be used as additive in oils for significantly improved the tribological performances. The self-assembly mechanism is confirmed by NMR. The as-prepared zwitterionic gels have good thermoreversible and thixotropic characteristics, which make them as potential high performance semi-solid lubricants. The tribological results showed that the gel lubricants possessed excellent friction-reducing and anti-wear properties compared with blank 500SN and Li-base grease with 2 wt% MoS2. The morphologies of the worn surfaces were analyzed by scanning electron microscope (SEM). The lubrication mechanism is proposed according to in-situ electrical contact resistance and the surface composition analysis at the worn surfaces.
Original language | English |
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Pages (from-to) | 55-65 |
Number of pages | 11 |
Journal | Tribology International |
Volume | 95 |
DOIs | |
State | Published - 1 Mar 2016 |
Externally published | Yes |
Keywords
- Boundary film
- Friction reduction and anti-wear
- Gel lubricants
- Zwitterionic Gelator