In situ surface assembly of core-shell TiO2-copper(I) cluster nanocomposites for visible-light photocatalytic reduction of Cr(VI)

Wei Ji; Jian Qu; Cheng An Li; Jing Wei Wu; Su Jing; Fei Gao; Yi Nong Lv; Chang Liu; Dun Ru Zhu; Xiao Min Ren; Wei Huang

doi:10.1016/j.apcatb.2016.12.041

In situ surface assembly of core-shell TiO₂-copper(I) cluster nanocomposites for visible-light photocatalytic reduction of Cr(VI)

Wei Ji, Jian Qu, Cheng An Li, Jing Wei Wu, Su Jing, Fei Gao, Yi Nong Lv, Chang Liu, Dun Ru Zhu, Xiao Min Ren, Wei Huang

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

1D loop chain copper(I) cluster, [Cu₂I₂L₂]_n, can be obtained based upon 9-(3-phenylselanyl-2-phenylselanylmethylpropyl)anthracene (L) and CuI. A facile in situ surface assembly strategy was designed to construct polymeric [Cu₂I₂L₂]_non the surface of TiO₂nanoparticles. The visible-light photocatalytic property of core-shell TiO₂-[Cu₂I₂L₂]_nwas confirmed by effective reduction of aqueous chromium(VI), showing a clear correlation to optical absorption (Eg = 2.8 eV). The key points of this strategy include high reactivity between copper(I) and soft selenium atom, efficient charge-transfer through polymeric cluster shell, and visible-light photoactivity of copper(I) halogen clusters.

Original language	English
Pages (from-to)	368-375
Number of pages	8
Journal	Applied Catalysis B: Environmental
Volume	205
DOIs	https://doi.org/10.1016/j.apcatb.2016.12.041
State	Published - 2017
Externally published	Yes

Keywords

Charge-transfer complex
Polymeric [CuIL]cluster
Selenoanthracene
TiO
Visible-light photocatalyst

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10.1016/j.apcatb.2016.12.041

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title = "In situ surface assembly of core-shell TiO2-copper(I) cluster nanocomposites for visible-light photocatalytic reduction of Cr(VI)",

abstract = "1D loop chain copper(I) cluster, [Cu2I2L2]n, can be obtained based upon 9-(3-phenylselanyl-2-phenylselanylmethylpropyl)anthracene (L) and CuI. A facile in situ surface assembly strategy was designed to construct polymeric [Cu2I2L2]non the surface of TiO2nanoparticles. The visible-light photocatalytic property of core-shell TiO2-[Cu2I2L2]nwas confirmed by effective reduction of aqueous chromium(VI), showing a clear correlation to optical absorption (Eg = 2.8 eV). The key points of this strategy include high reactivity between copper(I) and soft selenium atom, efficient charge-transfer through polymeric cluster shell, and visible-light photoactivity of copper(I) halogen clusters.",

keywords = "Charge-transfer complex, Polymeric [CuIL]cluster, Selenoanthracene, TiO, Visible-light photocatalyst",

author = "Wei Ji and Jian Qu and Li, {Cheng An} and Wu, {Jing Wei} and Su Jing and Fei Gao and Lv, {Yi Nong} and Chang Liu and Zhu, {Dun Ru} and Ren, {Xiao Min} and Wei Huang",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2017",

doi = "10.1016/j.apcatb.2016.12.041",

language = "英语",

volume = "205",

pages = "368--375",

journal = "Applied Catalysis B: Environmental",

issn = "0926-3373",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - In situ surface assembly of core-shell TiO2-copper(I) cluster nanocomposites for visible-light photocatalytic reduction of Cr(VI)

AU - Ji, Wei

AU - Qu, Jian

AU - Li, Cheng An

AU - Wu, Jing Wei

AU - Jing, Su

AU - Gao, Fei

AU - Lv, Yi Nong

AU - Liu, Chang

AU - Zhu, Dun Ru

AU - Ren, Xiao Min

AU - Huang, Wei

PY - 2017

Y1 - 2017

N2 - 1D loop chain copper(I) cluster, [Cu2I2L2]n, can be obtained based upon 9-(3-phenylselanyl-2-phenylselanylmethylpropyl)anthracene (L) and CuI. A facile in situ surface assembly strategy was designed to construct polymeric [Cu2I2L2]non the surface of TiO2nanoparticles. The visible-light photocatalytic property of core-shell TiO2-[Cu2I2L2]nwas confirmed by effective reduction of aqueous chromium(VI), showing a clear correlation to optical absorption (Eg = 2.8 eV). The key points of this strategy include high reactivity between copper(I) and soft selenium atom, efficient charge-transfer through polymeric cluster shell, and visible-light photoactivity of copper(I) halogen clusters.

AB - 1D loop chain copper(I) cluster, [Cu2I2L2]n, can be obtained based upon 9-(3-phenylselanyl-2-phenylselanylmethylpropyl)anthracene (L) and CuI. A facile in situ surface assembly strategy was designed to construct polymeric [Cu2I2L2]non the surface of TiO2nanoparticles. The visible-light photocatalytic property of core-shell TiO2-[Cu2I2L2]nwas confirmed by effective reduction of aqueous chromium(VI), showing a clear correlation to optical absorption (Eg = 2.8 eV). The key points of this strategy include high reactivity between copper(I) and soft selenium atom, efficient charge-transfer through polymeric cluster shell, and visible-light photoactivity of copper(I) halogen clusters.

KW - Charge-transfer complex

KW - Polymeric [CuIL]cluster

KW - Selenoanthracene

KW - TiO

KW - Visible-light photocatalyst

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U2 - 10.1016/j.apcatb.2016.12.041

DO - 10.1016/j.apcatb.2016.12.041

M3 - 文章

AN - SCOPUS:85008697735

SN - 0926-3373

VL - 205

SP - 368

EP - 375

JO - Applied Catalysis B: Environmental

JF - Applied Catalysis B: Environmental

ER -

In situ surface assembly of core-shell TiO₂-copper(I) cluster nanocomposites for visible-light photocatalytic reduction of Cr(VI)

Abstract

Keywords

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