Hybrid nanoarrays of Cu-MOFs@H-substituted graphdiyne with various levels of Lewis acidity for nitrate electroreduction

Jiahao Ma; Ru Wang; Biwen Wang; Jiaxin Luo; Qiuyu Zhang; Sifei Zhuo

doi:10.1039/d2cc06989j

Hybrid nanoarrays of Cu-MOFs@H-substituted graphdiyne with various levels of Lewis acidity for nitrate electroreduction

Jiahao Ma, Ru Wang, Biwen Wang, Jiaxin Luo, Qiuyu Zhang, Sifei Zhuo

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

To mimic enzymes in nature, a set of hybrid nanoarrays of Cu-MOFs sealed in hydrogen-substituted graphdiyne has been developed in order to serve as Lewis-acid-promoted catalysts. By regulating the electron-withdrawing capability of the ligands bridging Cu²⁺ sites, these Cu-MOFs provided different levels of Lewis acidity toward nitrate affinity, a feature crucial for nitrate-to-ammonia conversion.

Original language	English
Pages (from-to)	4348-4351
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	29
DOIs	https://doi.org/10.1039/d2cc06989j
State	Published - 13 Mar 2023

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abstract = "To mimic enzymes in nature, a set of hybrid nanoarrays of Cu-MOFs sealed in hydrogen-substituted graphdiyne has been developed in order to serve as Lewis-acid-promoted catalysts. By regulating the electron-withdrawing capability of the ligands bridging Cu2+ sites, these Cu-MOFs provided different levels of Lewis acidity toward nitrate affinity, a feature crucial for nitrate-to-ammonia conversion.",

author = "Jiahao Ma and Ru Wang and Biwen Wang and Jiaxin Luo and Qiuyu Zhang and Sifei Zhuo",

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AU - Ma, Jiahao

AU - Wang, Ru

AU - Wang, Biwen

AU - Luo, Jiaxin

AU - Zhang, Qiuyu

AU - Zhuo, Sifei

PY - 2023/3/13

Y1 - 2023/3/13

N2 - To mimic enzymes in nature, a set of hybrid nanoarrays of Cu-MOFs sealed in hydrogen-substituted graphdiyne has been developed in order to serve as Lewis-acid-promoted catalysts. By regulating the electron-withdrawing capability of the ligands bridging Cu2+ sites, these Cu-MOFs provided different levels of Lewis acidity toward nitrate affinity, a feature crucial for nitrate-to-ammonia conversion.

AB - To mimic enzymes in nature, a set of hybrid nanoarrays of Cu-MOFs sealed in hydrogen-substituted graphdiyne has been developed in order to serve as Lewis-acid-promoted catalysts. By regulating the electron-withdrawing capability of the ligands bridging Cu2+ sites, these Cu-MOFs provided different levels of Lewis acidity toward nitrate affinity, a feature crucial for nitrate-to-ammonia conversion.

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U2 - 10.1039/d2cc06989j

DO - 10.1039/d2cc06989j

M3 - 文章

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Hybrid nanoarrays of Cu-MOFs@H-substituted graphdiyne with various levels of Lewis acidity for nitrate electroreduction

Abstract

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